Vitoriaio‚Μ“ͺ‚ɁMj,L., Soler,A., Canala,Ai“ͺ‚ɁMj. and Otero,N.(2008): Environmental isotopes (N, S, C, O, D) to determine natural attenuation processes in nitrate contaminated waters: Example of Osona (NE Spain). Applied Geochemistry, 23, 3597-3611.

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wAbstract
@Nitrate-contaminated groundwater from an aquifer in the Osona region (NE Spain) was chemically and isotopically (ƒΒ15NNO3, ƒΒ18ONO3, ƒΒ34SSO4, ƒΒ18OSO4, ƒΒD, ƒΒ18OH2O, and ƒΒ13CDIC) characterized. Diffuse-NO3- contamination reached values of 366 mg/L. Nearly 75“ of the 37 sampled sites had higher concentrations than the 50 mg/L in NO3- limit for drinking water. To identify the source of pollution ƒΒ15NNO3 and ƒΒ18ONO3 were used with results, for most samples, in the range of pig manure NO3-. Nitrification processes were evaluated by means of the ƒΒ18 of NO3- and water. Isotopic data suggested that natural attenuation of NO3- was taking place. This process was confirmed using the ƒΒ18ONO3 coupled with the NO3-/Cl- ratio, avoiding the influence of continuous NO3- inputs. A further insight on denitrification processes was obtained by analyzing the ions involved in denitrification reactions. Although the role of organic matter oxidation could neither be confirmed nor discarded, this approach showed a link between denitrification and pyrite oxidation. Therefore, in areas with no adequate infrastructure (e.g. multipiezometers), such as the one studied, this approach could be useful for implementing better water management.x

1. Introduction
2. Study area
3. Sampling and analysis
4. Results and discussion
@4.1. Groundwater quality
@4.2. Stable isotopes
@4.3. Evaluation of fractionation processes affecting N compounds
@4.4. Evaluation of the natural attenuation: the denitrification
5. Conclusions
Acknowledgements
References


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