『Abstract
Ammonium release from sediments has significant effects on the
water quality in eutrophic lakes. In this study, the ammonium
release kinetics and adsorption-desorption processes were investigated
in 13 sediments of 6 shallow lakes from the middle and lower reaches
of Yangtze River region, China. The results show that First Order
Model best described the ammonium release process, the maximal
release capacity had a strong correlation with organic matter
(OM), cationic exchange capacity (CEC), total nitrogen (TN) and
total phosphorus (TP). But it only had a weak correlation with
Fe, Ca and Al. The ammonium release capacity in more polluted
sediments was higher than that in less polluted sediments. The
average release rate within 0-5 min was the highest among the
experimental period, the amount released within 0-5 min accounted
for approximately 50-70% of the total release capacity. he ammonium
release rate had a significant and positive correlation with OM.
But it did not have a strong correlation with TN, TP, Fe, Ca and
Al. The ammonium potential release capacity (obtained when the
water/sediment ratio was about 2,500) had strong and positive
relation with OM and maximal release capacity, and it may provide
useful information for the sediment release risk assessment. Henry
Model best described the ammonium sorption isotherms, and ammonium
adsorption-desorption equilibrium concentration can be considered
as the ammonium release threshold to assess the release risk in
the sediments
Keywords: Ammonium; Release; Kinetics; Lake; Sediments』
Introduction
Area description, materials and methods
Study area and sediment sampling
Ammonium release kinetics experiments
ammonium potential release capacity
Ammonium adsorption-desorption equilibrium concentration
Results and discussion
Ammonium release kinetics
Ammonium maximal release capacity
ammonium release rate
Ammonium potential release capacity
Ammonium adsorption-desorption equilibrium concentration
Conclusions
Acknowledgments
References