wAbstract
@The nitrate of groundwater in the Gimpo agricultural area, South
Korea, was characterized by means of nitrate concentration, nitrogen-isotope
analysis, and the risk assessment of nitrogen. The groundwaters
belonging to Ca-(Cl+NO3) and Na-(Cl+NO3) types displayed a higher average NO3-
concentration (79.4 mg/L), exceeding the Korean drinking water
standard (44.3 mg/L NO3-). The
relationship between Β18O-NO3-
values and Β15N-NO3-
values revealed that nearly all groundwater samples with Β15N-NO3- of +7.57 to +13.5ρ were affected
by nitrate from manure/sewage as well as microbial nitrification
and negligible denitrification. The risk assessment of nitrate
for groundwater in the study area was carried out using the risk-based
corrective action model since it was recognized that there is
a necessity of a quantitative assessment of health hazard, as
well as a simple estimation of nitrate concentration. All the
groundwaters of higher nitrate concentration than the Korean drinking
water standard (44.3 mg/L NO3-)
belonged to the domain of the hazard index 1, indicating no health
hazard by nitrate in groundwater in the study area. Further, the
human exposure to the nitrate-contaminated soil was below the
critical limit of non-carcinogenic risk.
Keywords: Nitrate; Groundwater; Nitrogen isotope; Agricultural
area; Geochemistry; Risk assessmentx
Introduction
Study area
Methods of sampling and chemical analyses
Results and discussion
@Nitrate contamination and origins of the groundwater
@Risk assessment of nitrate in groundwater
Conclusions
Acknowledgments
References