Cheong,J.-Y., Hamm,S.-Y., Lee,J.-H., Lee,K.-S. and Woo,N.-C.(2012): Groundwater nitrate contamination and risk assessment in an agricultural area, South Korea. Environ. Earth Sci., 66, 1127-1136.

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wAbstract
@The nitrate of groundwater in the Gimpo agricultural area, South Korea, was characterized by means of nitrate concentration, nitrogen-isotope analysis, and the risk assessment of nitrogen. The groundwaters belonging to Ca-(Cl+NO3) and Na-(Cl+NO3) types displayed a higher average NO3- concentration (79.4 mg/L), exceeding the Korean drinking water standard (ƒ44.3 mg/L NO3-). The relationship between ƒΒ18O-NO3- values and ƒΒ15N-NO3- values revealed that nearly all groundwater samples with ƒΒ15N-NO3- of +7.57 to +13.5ρ were affected by nitrate from manure/sewage as well as microbial nitrification and negligible denitrification. The risk assessment of nitrate for groundwater in the study area was carried out using the risk-based corrective action model since it was recognized that there is a necessity of a quantitative assessment of health hazard, as well as a simple estimation of nitrate concentration. All the groundwaters of higher nitrate concentration than the Korean drinking water standard (ƒ44.3 mg/L NO3-) belonged to the domain of the hazard index ƒ1, indicating no health hazard by nitrate in groundwater in the study area. Further, the human exposure to the nitrate-contaminated soil was below the critical limit of non-carcinogenic risk.

Keywords: Nitrate; Groundwater; Nitrogen isotope; Agricultural area; Geochemistry; Risk assessmentx

Introduction
Study area
Methods of sampling and chemical analyses
Results and discussion
@Nitrate contamination and origins of the groundwater
@Risk assessment of nitrate in groundwater
Conclusions
Acknowledgments
References


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