Stelzer,R.S., Drover,D.R., Eggert,S.L. and Muldoon,M.A.(2011): Nitrate retention in a sand plains stream and the importance of groundwater discharge. Biogeochemistry, 103, 91-107.

『砂平野の流れにおける硝酸塩保留および地下水流出の重要性』


Abstract
 We measured net nitrate retention by mass balance in a 700-m upwelling reach of a third-order sand plains stream, Emmons Creek, from January 2007 to November 2008. Surface water and groundwater fluxes of nitrate were determined from continuous records of discharge and from nitrate concentrations based on weekly and biweekly sampling at three surface water stations and in 23 in-stream piezometers, respectively. Surface water nitrate concentration in Emmons Creek was relatively high (mean of 2.25 mg NO3-N l-1) and exhibited strong seasonal variation. Net nitrate retention averaged 429 mg NO3-N m-2 d-1 and about 2% of nitrate inputs to the reach. Net nitrate retention was highest during the spring and autumn when groundwater discharge was elevated. Groundwater discharge explained 57-65% of the variation in areal net nitrate retention. Specific discharge and groundwater nitrate concentration varied spatially. Weighting groundwater solute concentrations by specific discharge improved the water balance and resulted in higher estimates of nitrate retention. Our results suggest that groundwater inputs of nitrate can drive nitrate retention in streams with high groundwater discharge.

Keywords: Focused discharge; Groundwater; Mass-balance; Nitrogen; Sediments』

Introduction
Methods
 Site description
 Surface water stations and piezometers
 Nutrient sampling - surface water
 Nutrient sampling - groundwater
 Hydrology - surface water
 Hydrology - groundwater
 Nutrient analysis
 Mass balance model
Results
 Hydrology
 Nutrient concentrations
 Nitrate retention and flux
Discussion
 Hydrology
 Nitrate retention
 Mechanisms
 Stream ecosystem comparison
 Nitrate time series
 Implications for nitrogen removal from ecosystems
Acknowledgements
References


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