『Abstract
We measured net nitrate retention by mass balance in a 700-m
upwelling reach of a third-order sand plains stream, Emmons Creek,
from January 2007 to November 2008. Surface water and groundwater
fluxes of nitrate were determined from continuous records of discharge
and from nitrate concentrations based on weekly and biweekly sampling
at three surface water stations and in 23 in-stream piezometers,
respectively. Surface water nitrate concentration in Emmons Creek
was relatively high (mean of 2.25 mg NO3-N
l-1) and exhibited strong seasonal variation. Net nitrate
retention averaged 429 mg NO3-N m-2
d-1 and about 2% of nitrate inputs to the reach. Net
nitrate retention was highest during the spring and autumn when
groundwater discharge was elevated. Groundwater discharge explained
57-65% of the variation in areal net nitrate retention. Specific
discharge and groundwater nitrate concentration varied spatially.
Weighting groundwater solute concentrations by specific discharge
improved the water balance and resulted in higher estimates of
nitrate retention. Our results suggest that groundwater inputs
of nitrate can drive nitrate retention in streams with high groundwater
discharge.
Keywords: Focused discharge; Groundwater; Mass-balance; Nitrogen;
Sediments』
Introduction
Methods
Site description
Surface water stations and piezometers
Nutrient sampling - surface water
Nutrient sampling - groundwater
Hydrology - surface water
Hydrology - groundwater
Nutrient analysis
Mass balance model
Results
Hydrology
Nutrient concentrations
Nitrate retention and flux
Discussion
Hydrology
Nitrate retention
Mechanisms
Stream ecosystem comparison
Nitrate time series
Implications for nitrogen removal from ecosystems
Acknowledgements
References