『Abstract
This paper describes the implementation of process-based models
reflecting relative groundwater nitrate vulnerability of the shallow
alluvial Lower Savinja Valley (LSV) aquifer in Slovenia. A spatially
explicit identification of the potentially vulnerable priority
areas within groundwater bodies at risk from a chemical point
of view is being required for cost-effective measures and monitoring
planning. The shallow LSV unconfined aquifer system consists of
high-permeable Holocene and middle- to low-permeable Pleistocene
gravel and sand, with a maximum thickness of about 30 m, mainly
covered by shallow eutric fluvisoils or variously deep eutric
cambisoil. The hydrogeological parameters, e.g. the depth to the
groundwater, hydrological role of the topographic slope, etc.
usually used in different point count schemes are, in the case
of the lowland aquifer and shallow groundwater, spatially very
uniform with low variability. Furthermore, the parametric point
count methods are generally not able to illustrate and analyze
important physical processes, and validation of the results is
difficult and expensive. Instead of a parametric point count scheme,
we experimentally used the Arc-WofE extension for weights-of-evidence
(EofE) modelling. All measurement locations with a concentration
higher than the value of 20 mg NO3-
per litre of groundwater have been considered as training points
(173), and the three process-based models generalized output layers
of groundwater recharge (GROWA), nitrate leached from the soil
profile (SWAT) and groundwater flow velocity (FEFLOW), served
as evidential themes. The technique is based on the Bayesian idea
of phenomena occurrences probability before (prior probability)
and after consideration of any evidential themes (posterior probability),
which were measured by positive and negative weights as an indication
of the association between a phenomena and a prediction pattern.
The response theme values describe the relative probability than
a 100 × 100 m spatial unit will have a groundwater nitrate concentration
higher than the training points' limit values with regard to prior
probability value. The lowest probability of groundwater nitrate
occurrence is in the parts of the LSV aquifer, which are known
as anoxic condition areas with very likely denitrification processes.
The cross-validation of the dissolved oxygen and dissolved nitrate
response theme confirmed the accuracy of the groundwater nitrate
prediction. The WofE model results very clearly indicate regional
groundwater nitrate distribution and enable spatial prediction
of the probability for increased groundwater nitrate concentration
in order to plan the groundwater nitrate reduction measures and
optimize the programme for monitoring the effects of these measures.
Keywords: Groundwater nitrate vulnerability; Process-based models;
Weights-of-evidence; Lower Savinja Valley (Slovenia)』
Introduction
Study area and field measurements
Study method
Evidential themes
Groundwater recharge
Nitrogen load in seepage water
Groundwater flow velocity
Analysis and discussion
Conclusion
Acknowledgments
References