『Abstract
Seasonal and diurnal variations of in-stream NO3-N
concentration oscillations were studied through high-frequency
measurements of stream-water's physical, chemical parameters (in-stream
NO3-N concentration, water temperature, dissolved
oxygen, pH) and hydrometeorological variables (stream discharge,
solar radiation) under hydrologically stable conditions. The study
was carried out in 2006, within the 42 km2 forested
Padez(zの頭にv) stream watershed in the southwestern
part of Slovenia, which is characterized by distinctive hydrogeological
settings (flysch) and climate conditions (transitional area between
the Mediterranean and continental climate). Fine temporal data
resolution (15-min interval) enabled identification of the factors
responsible for seasonal variability in the diurnal pattern of
the streamwater NO3-N concentrations versus
seasonal and diurnal behavior of meteorological and other water
chemistry constituents. The observed seasonal variability of in-stream
NO3-N daily oscillations indicates the important
role of primary production uptake, particularly during seasons
when deciduous vegetation is dormant and light levels in the stream
are high. Highest daily NO3-N concentration
amplitudes (0.3 mg/l-N) and daily changes in the NO3-N
flux (0.4-0.5 g/s-N) were observed in spring; the NO3-N
concentration oscillations in summer showed a considerably smaller
effect of the in-stream uptake (maximum NO3-N
daily concentration amplitude 0.1 mg/l-N; daily change in the
NO3-N flux 0.02 g/s-N). Seasonal shifts in
the timing of daily maximum (up to 6 h) and minimum NO3-N
concentrations (between 1 and 3 h) provided some additional indications
of seasonal changes in the in-stream primary production uptake
and its relation to the terrestrial component of the forested
watershed.
Keywords: Diurnal oscillations; Forested watersheds; High-frequency
measurements; Seasonality; Slovenia; In-stream nitrate』
Introduction
Study area
Methods
Data acquisition
Time series analysis
Results
Spatial variations in the streamwater NO3-N
concentrations
Time series of the streamwater chemistry and meteorological conditions
Discussion
Seasonal pattern of the in-stream NO3-N
concentration and implications of N status of the watershed
Seasonal changes in amplitude of in-stream NO3-N
concentration diurnal oscillations
Seasonal shifts in the timing of daily minimum and maximum streamwater
NO3-N concentration
Terrestrial versus in-stream processing of NO3-N
Conclusions
Acknowledgments
References