『Abstract
The purpose of this study is to show the results of the Italian
research project of national interest (PRIN) launched in 2006
and finished in 2008, concerning the “assessment of groundwater
contamination risk by nitrates assessment”. The project verified
the IPNOA method for nitrate groundwater contamination risk assessment
in four test-sites of Italy. The IPNOA is a parametric index which
assesses the potential hazard of nitrate contamination originating
from agriculture on a regional scale. The method integrates two
categories of parameters: the hazard factors (HF), which represent
all farming activities that cause, or might cause, an impact on
soil quality in terms f nitrate (use of fertilisers, application
of livestock and poultry manure, food industry wastewater and
urban sludge), and the control factors (CF) which adapt the hazard
factors to the characteristics of the site (geographical location,
climate conditions and agronomic practices). Finally, the Potential
Risk Map is obtained by coupling the potential hazard of nitrate
pollution (IPNOA) and the aquifer Contamination Vulnerability
Map. The project was carried out by five Research Units (RU) from
the Politecnico di torino, Universities of Piacenza, Florence,
Naples and Palermo. The geochemistry of groundwaters from the
four test-sites was studied to determine the distribution of nitrate,
and to evaluate groundwater chemical facies. All the study areas
are affected by groundwater nitrate contamination and often by
hydrogeochemical peculiarities. In some cases isotopic study,
δ18O-NO3, δ15N-NO3, allowed to differentiate nitrates of chemical
fertilisers from those of biological origin, as well as denitrification
processes.
Keywords: Groundwater contamination; Nitrate; Groundwater vulnerability;
Risk assessment; Italy』
1. Introduction
2. Methods
2.1. The model SINTACS R5 for the assessment of aquifer contamination
vulnerability
2.2. The agricultural nitrate hazard index: IPNOA
2.2.1. IPNOA calculation
2.2.2. Considerations about the IPNOA method
2.3. The index of hazard from nitrates of household origin: IPNOC
3. Potential nitrate risk of contamination of a plain in the province
of Cuneo (NW Italy)
3.1. The Fossano area
3.2. Considerations on the potential nitrate risk map of the
Fossano area
4. Pollution risk for groundwater from nitrates of agricultural
and household origin in the Cecina Plain (Tuscany, central Italy)
4.1. Evaluation of the groundwater pollution risk in the
Cecina Plain
4.2. Water geochemistry and isotopic composition of nitrate in
the Cecina Plain
5. Nitrate contamination risk mapping and influence of the hydrogeochemical
pattern in the northern part of the Volturno River Plain
5.1. Hydrogeology and hydrogeochemistry of the northern part
of the Volturno River Plain
5.2. Nitrate groundwater contamination risk assessment using
the IPNOA method in the northern part of the Volturno River Plain
6. Hydrogeological resources, hydrogeochemistry and groundwater
nitrate contamination risk assessment of the Ribera test site
(Sicily, Italy)
6.1. Geochemical context of the Ribera test site
6.2. The map of intrinsic nitrate contamination risk from agricultural
sources at the Ribera test site
7. Conclusions
References