『Abstract
In karst aquifers, contaminated recharge can degrade spring water
quality, but quantifying the rapid recharge (quick flow) component
of spring flow is challenging because of its temporal variability.
Here, we investigate the use of nitrate in a two-endmember mixing
model to quantify quick flow in Barton Springs, Austin, Texas.
Historical nitrate data from recharging creeks and Barton Springs
were evaluated to determine a representative nitrate concentration
for the aquifer water endmember (1.5 mg/L) and the quick flow
endmember (0.17 mg/L for nonstormflow conditions and 0.25 mg/L
for stormflow conditions). Under nonstormflow conditions for 1990
to 2005, model results indicated that quick flow contributed from
0% to 55% of spring flow. The nitrate-based two-endmember model
was applied to the response of Barton Springs to a storm and results
compared to those produced using the same model with δ18O
and specific conductance (SC) as tracers. Additionally, the mixing
model was modified to allow endmember quick flow values to vary
over time. Of the three tracers, nitrate appears to be the most
advantageous because it is conservative and because the difference
between the concentrations in the two endmembers is large relative
to their variance. The δ18O-based model was very sensitive
to variability within the quick flow endmember, and SC was not
conservative over the timescale of the storm response. We conclude
that a nitrate-based two-endmember mixing model might provide
a useful approach for quantifying the temporally variable quick
flow component of spring flow in some karst systems.』
Introduction
Study site
Evaluation of nitrate concentrations and model
Results
Base flow conditions
Stormflow conditions
Discussion
Conclusions
Acknowledgment
References