Schmidt,B.H.M. and Matzner,E.(2009): Abiotic reaction of nitrite with dissolved organic carbon? Testing the Ferrous Wheel Hypothesis. Biogeochemistry, 93, 291-296.

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wAbstract
@The Ferrous Wheel Hypothesis (Davidson et al. 2003) postulates the abiotic formation of dissolved organic N (DON) in forest floors, by the fast reaction of NO2- with dissolved organic C (DOC). we investigated the abiotic reaction of NO2- with dissolved organic matter extracted from six different forest floors under oxic conditions. Solutions differed in DOC concentrations (15-60 mg L-1), NO2- concentrations (0, 2, 20 mg NO2--N L-1) and DOC/DON ratio (13.4-25.4). Concentrations of added NO2- never decreased within 60 min, therefore, no DON formation from added NO2- took place in any of the samples. Our results suggest that the reaction of NO2- with natural DOC in forest floors is rather unlikely.

Keywords: Abiotic nitrite immobilization; Dissolved organic carbon; Dissolved organic nitrogen; Ferrous Wheel Hypothesisx

Introduction
Materials and methods
Results and discussion
Acknowledgments
References


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