wAbstract
@Soil and sand fine particles, which may be resuspended as fine
dust in the atmosphere, contain a variety of anthropogenic and
natural organic components. Samples of fine soil and sand particles
(sieved to ƒ125ƒÊM) were collected from the Riyadh area in the
summer of 2003 and extracted with a mixture of dichloromethane
and methanol (3:1, v:v(. The derivatized total extracts were analyzed
by gas chromatography-mass spectrometry in order to characterize
the composition and sources of the organic components. Both anthropogenic
and natural biogenic inputs were the major sources of the organic
compounds in these extracts. Discarded plastics and vehicular
emission products were the major anthropogenic sources in the
fine particles from populated areas of the city. their tracers
were plasticizers, UCM, n-alkanes, hopanes and tracers of steranes.
Vegetation was the major natural source of organic compounds in
samples from outside Riyadh and included n-alkanols, n-alkanoic
acids, n-alkanes, methyl alkanoates, sterols and triterpenoids.
Carbohydrates had high concentrations (42-54“) in all samples
and indicate sources from decomposition of cellulose and/or the
presence of viable microbiota such as bacteria and fungi. The
results were also compared with the data obtained in winter 2002
and showed that anthropogenic inputs were higher in summer than
in winter, whereas the opposite trend was observed for natural
inputs.
Keywords: Biomarkers; Carbohydrates; Lipids; Petroleum residues;
Plasticizers; UCMx
Introduction
Experimental methods
@Sampling and extraction procedure
@Instrumental analysis
Results and discussion
@Anthropogenic sources
@Natural biogenic sources
@Anthropogenic versus natural sources
Conclusions
Acknowledgments
References