『Abstract
Nador lagoon sediments (East Morocco) are contaminated by industrial
iron mine tailings, urban dumps and untreated wastewaters from
surrounding cities. The lagoon is an ecosystem of biological,
scientific and socio-economic interests but its balance is threatened
by pollution already marked by biodiversity changes and a modification
of foraminifera and ostracods shell structures. The aim of the
study is to assess the heavy metal contamination level and mobility
by identifying the trapping phases. The study includes analyses
by ICP-AES and ICP-MS, of, respectively, major (Si, Al, Mg, Ca,
Fe, Mn, Ti, Na, K, P) and trace elements (Sr, Ba, V, Ni, Co, Cr,
Zn, Cu, As, Pb, Cd) in sediments and suspended matter, heavy metals
enrichment factors calculations and sequential extractions. Results
show that sediments contain Zn, Cu, Pb, V, Cr, Co, As, Ni with
minimum and maximum concentrations, respectively, of 4-1190μg/g,
4-466μg/g, 11-297μg/g, 11-194μg/g, 9-139μg/g, 1-120μg/g, 4-76μg/g,
2-62μg/g. High concentrations in Zn are also present in suspended
matter. The enrichment factors show contamination in Zn, Pb and
As firstly induced by the mining industry and secondly by unauthorized
dumps and untreated wastewaters. Cr and Ni are bound to clays,
whereas V, Co, Cu and Zn are related to oxides. Thus, the risk
in metal mobility is for the latter elements and lies in the oxidation-reduction-changing
conditions of sediments.
Keywords: Geochemistry; Trace elements contamination; Sediments;
Suspended matter; Nador lagoon』
Introduction
Study area
Materials and methods
Sampling
Mineralogy
Geochemistry and enrichment factors
Sequential extraction
Suspended matter analysis
Results
Mineralogy
Heavy metal concentrations in lagoon sediments
Correlation between major and trace elements
Contamination level
Heavy metals trapping phases
Heavy metals in suspended matter
Conclusion
Acknowledgments
References