『Abstract
A total of 49 elements have been identified in 338 coastal sea
sediment samples collected from an area situated off the Ise-Tokai
region of Japan for a nationwide marine geochemical mapping project.
The spatial distribution patterns of the elemental concentrations
in coastal seas along with the existing geochemical maps in terrestrial
areas were used to define the natural geochemical background variation,
mass transport, and contamination processes. The elemental concentrations
of coastal sea sediments are determined primarily by particle
size and regional differences. Most elemental concentrations increase
with a decrease in particle size. Some elements such as Ca, Mn,
and Yb are found to exist in large quantities in coarse particles
containing calcareous shells, Fe-Mn oxides, and felsic volcanic
sediments. Regional differences reflect the mass transfer process
from terrestrial areas to coastal seas and the influence of the
local marine geology. An analysis of variance (ANOVA) reveals
that for many elements, the particle size effect is predominant
over regional difference. The mean chemical compositions of coastal
sea sediments are similar to those of stream sediments in adjacent
terrestrial areas and in the upper crust of Japan. This observation
supports the fact that coastal sea sediments have certainly originated
from terrestrial materials. However, the spatial distributions
of elemental concentrations are bot always continuous between
the land and coastal seas. The scale of mass movement observed
in marine geochemical maps occurs at a distance of 20 km from
the river mouth. A detailed examination of the spatial distribution
patterns of K (K2O) and Cr concentrations
suggests that terrestrial materials supplied through rivers are
deposited near the shore initially, and then gravity-driven processes
shift the sediments deeper into the basin. Contamination with
heavy metals such as Zn, Cd and Pb was observed in coastal bays
surrounded by urban and industrial areas. It is noteworthy that
the areas with the highest concentration of these elements usually
do not occur near the shore (not near the contamination source)
but at the center of the bay. Unexpected low concentrations of
Zn, Cd and Pb near shore may either be due to a decreased anthropogenic
load in the most recent sediments or to dilution by unpolluted
flood sediments.』
1. Introduction
2. Study area
3. Materials and methods
4. Geochemical map preparation
5. Results
5.1. Spatial distribution patterns of elemental concentrations
in the coastal sea and adjoining terrestrial areas
5.2. Variation in elemental concentrations in coastal sea sediments
with particle size
6. Discussion
6.1. Regional differences found in elemental distributions
6.2. Particle size dependence of elemental concentrations in
coastal sea sediments
6.3. Major factors controlling the distribution of elements in
coastal seas
6.3.1. Relationships between regional differences and particle
size effects
6.3.2. Analysis of variance (ANOVA) to test the effects of particle
size and regional difference
6.3.3. Interpretation of the results obtained by ANOVA
6.4. Mass transport processes in the coastal sea
6.5. Distribution of anthropogenic materials in coastal bays
6.6. Comparison of elemental abundance in coastal sea sediments,
stream sediment, and Japanese and continental upper crusts
7. Conclusions
Acknowledgements
References