wAbstract
@Based on ten heavy metals collected twice annually at 59 sites
from 1998 to 2004, enrichment factors (EFs), principal component
analysis (PCA) and multivariate linear regression of absolute
principal component scores (MLR-APCS) were used in identification
and source apportionment of the anthropogenic heavy metals in
marine sediment. EFs with Fe as a normalizer and local background
as reference values was properly tested and suitable in Hong Kong,
and Zn, Ni, Pb, Cu, Cd, Hg and Cr mainly originated from anthropogenic
sources, while Al, Mn and Fe were derived from rocks weathering.
Rotated PCA and GIS mapping further identified two types of anthropogenic
sources and their impacted regions: (1) electronic industrial
pollution, riparian runoff and vehicle exhaust impacted the entire
Victoria Harbour, inner Tolo Harbour, Eastern Buffer, inner Deep
Bay and Cheung Chau; and (2) discharges from textile factories
and paint, influenced Tsuen Wan Bay and Kwun Tong typhoon shelter
and Rambler Channel. In addition, MLR-APCS was successfully introduced
to quantitatively determine the source contributions with uncertainties
almost less than 8“: the first anthropogenic sources were responsible
for 50.0, 45.1, 86.6, 78.9 and 87.5“ of the Zn, Pb, Cu, Cd and
Hg, respectively, whereas 49.9“ of the Ni and 58.4“ of the Cr
came from the second anthropogenic sources.
Keywords: Heavy metals; Marine sediment; Source apportionment; Enrichment factors; Multivariate statistics; GISx
Introduction
Materials and methods
@Study area and sampling methods
@Enrichment factors
@Multivariate analyses and data transformation
Results and discussion
@Data pretreatment
@Differentiation between natural and anthropogenic elements
@Potential source identification
@Source contributions for each element
Conclusion
Acknowledgments
References