wAbstract
@The variations of ย17O andย18O in recent
meteoric waters and in ice cores have proven to be an important
tool for investigating the present and past hydrologic cycle.
In order to close significant information gaps in the present
distribution of ย17O and ย18O of meteoric
water, we have run precise measurements, with respect to VSMOW,
on samples distributed globally from low to high latitudes. Based
on the new and existing data, we present the Global Meteoric Water
Line (GMWL) for ย17O and ย18O as:
@@@ln (ย17O + 1) = 0.528 ln (ย18O + 1) +
0.000033 (R2 = 0.99999)
@In addition to meteoric water, we carried out the first measurements
of seawater from the Pacific and Atlantic oceans with respect
to VSMOW. The obtained results show that the slope of the trend
line ln (ย17O + 1) vs. ln (ย18O + 1) of
seawater samples is 0.528, the same as for meteoric water, but
the regression intercept is -5 per meg. Thus, the positive intercept
in the GMWL indicates an excess of 17O in meteoric
waters with respect to the ocean. An excess (or depletion) of
17O in water is defined as:
@@ 17O-excess = ln (ย17O + 1) - 0.528 (ย18O
+ 1)
@Most meteoric water samples have positive 17O-excess
of varying magnitudes with an average of 37 per meg with respect
to VSMOW. We explain low these positive values originate from
evaporation of sea water into marine air, which is undersaturated
in water vapor, and how subsequent increase of 17O-excess
occurs when atmospheric vapor condenses to form liquid and solid
precipitation. We also clarify the effect of excessive evaporation
on 17O-excess. Finally, based on the new results on
17O-excess of seawater we recalculated the relationship
of ย17O vs. ย18O in vapor diffusion in air
as 18ฟdiff = 1.0096.x
1. Introduction
2. Experimental
@2.1. Isotopic analyses
@2.2. Isotopic fractionations and notations
3. Results
@3.1. Seawater
@3.2. Meteoric waters
@3.3. Open pan experiment
4. Discussion
@4.1. The ย'17O vs. ย'18O slope in meteoric
waters
@4.2. The origin of 17O-excess in meteoric waters
@4.3. Variations of 17O -excess in polar precipitation
@4.4. Lowering of 17O-excess by excessive evaporation
5. Conclusions
Acknowledgments
References