『Abstract
For a half century, total suspended solids (TSS) has been the
most commonly utilized particulate matter (PM) gravimetric index
for wastewater. While TSS has been extended to urban runoff, runoff
phenomena are unique. Runoff is unsteady and transports heterodisperse
inorganic granulometry, giving rise to the PM index, suspended
sediment concentration (SSC). With respect to PM-associated chemical
oxygen demand (CODp) in runoff, it is hypothesized
that, while the TSS method can represent effluent CODp,
the SSC method is required to represent influent CODp.
CODp and PM indices (TSS and SSC) for runoff
events with mass balances and manual sampling are analyzed to
investigate this hypothesis. This study examined a series of rainfall-runoff
events captured from an instrumented fully paved urban catchment
subject to traffic loadings in Baton Rouge, LA. Results indicate
TSS generated substantial event-based mass balance errors for
CODp and Δmp (mg/g) across a hydrodynamic
separator (HS) as compared to SSC. TSS underestimates sediment-bound
COD (>75μm), a significant portion (maximum of 63% and median
of 50%) of influent load. Negative bias by the TSS method for
influent CODp load increases as the heterodisperse
particle size distribution becomes coarser. Above a PM of 250
mg/L, underestimation of CODp by the TSS
method is statistically significant. Utilizing the SSC method,
CODp reduction by a HS upstream of a batch
clarifier (BC) indicates that a HS does not provide CODp
reduction, compared to a BC with 60 min of residence time. Representative
PM and CODp assessment suggests frequent
BMP and drainage system maintenance to ensure proper operation
and reduce pollutant elution.
Keywords: Particulate matter; COD; TSS; Particle size distribution;
BMP; Unit operations』
1. Introduction
1.1. Oxygen demand indices for urban rainfall runoff
1.2. Particulate matter indices for urban rainfall runoff
1.3. Heterodisperse PSDs and subsampling TSS
2. Objectives
3. Methodology
3.1. Urban-paved watershed and treatment facility
3.2. Wastewater sample and urban atmospheric rainfall collection
3.3. PSD and COD (TSS and SSC method) analysis
3.4. Phase fractionation of CODT between
CODP fractions and CODd
3.5. PM fraction analyses
3.6. CODp concentration (mp)
(mg/g)
3.7. Mass balance, QA/QC, and statistical analysis
4. Results and discussion
4.1. Comparison of PSD and organic content between wastewater
and urban runoff
4.2. BMP performance for CODp characterized
by TSS and SSC methods
4.3. SSC and TSS as a measure of particulate-bound COD in rainfall
runoff
4.4. The role of PSDs on COD concentration measurement by TSS
and SC method
4.5. PLM to model relationship between PM and CODp
4.6. Transport of CODp associated
with three size fractions and CODd in urban
runoff
4.7. Treatment performance of HS, BC, and both for CODp
and CODd in urban runoff
4.8. Comparison of CODT in urban runoff,
atmospheric rainfall, and wastewater with literature
5. Conclusions
Nomenclature
References