『Abstract
Throughout the last few decades, sulfate concentrations in streamwater
have received considerable attention due to their dominant role
in anthropogenic acidification of surface waters. The objectives
of this study conducted in the Oldman River Basin in Alberta (Canada)
were to determine the influence of geology, land use and anthropogenic
activities on sources, concentrations and fluxes of riverine sulfate
on a watershed scale. This was achieved by combining hydrological,
chemical and isotopic techniques. Surface water samples were collected
from the main stem and tributaries of the Oldman River on a monthly
basis between December 2000 and March 2003 and analyzed for chemical
and isotopic compositions. At a given sampling site, sulfate sources
were primarily dependent on geology and did not vary with time
or flow condition. With increasing flow distance a gradual shift
from δ34S values >10‰ and δ18O values >0‰
of riverine sulfate indicating evaporite dissolution and soil-derived
sulfate in the predominantly forested headwaters, to negative
δ34S and δ18O values suggested that sulfide
oxidation was the predominant sulfate source in the agriculturally
used downstream part of the watershed. Significant increases in
sulfate concentrations and fluxes with downstream distance were
observed, and were attributed to anthropogenically enhanced sulfide
oxidation due to the presence of an extensive irrigation drainage
network with seasonally varying water levels. Sulfate-S exports
in an artificially drained subbasin (64 kg S/ha/yr) were found
to exceed those in a naturally drained subbasin (4 kg S/ha/yr)
by an order of magnitude. Our dataset suggests that the naturally
occurring process of sulfide oxidation has been enhanced in the
Oldman River Basin by the presence of an extensive network of
drainage and irrigation canals.
Keywords: Watershed; Sulfate; Stable isotopes; Sulfide oxidation;
Anthropogenic activities』
1. Introduction
2. Study area
2.1. Description
2.2. Geology and soils
3. Materials and methods
3.1. Sampling
3.2. Concentration and isotope measurements
4. Results
4.1. Concentration, flux, and isotopic composition of sulfate
in tributaries
4.2. Concentration, flux, and isotopic composition of sulfate
in the Oldman River
5. Discussion
5.1. Sulfate sources at respective sampling sites
5.2. Influence of geology and land use on sulfate sources and
fluxes
5.3. Anthropogenic control on riverine sulfate loading
6. Conclusions
Acknowledgments
References