wAbstract
@We used the dual isotope method to study differences in nitrate
export in two subwatersheds in Vermont, USA. Precipitation, soil
water and streamwater samples were collected from two watersheds
in Camels Hump State Forest, located within the Green Mountains
of Vermont. These samples were analyzed for the Β15N
and Β18O of NO3-. The
range of ΒN-NO3- values overlapped,
with precipitation -4.5ρ to +2.0ρ (n = 14), soil solution -10.3ρ
to +6.2ρ (n = 12) and streamwater +0.3ρ to +3.1ρ (n = 69). The
Β18O of precipitation NO3-
(mean 46.8}11.5ρ) was significantly different (P0.001) from that
of the stream (mean 13.2}4.3ρ) and soil waters (mean 14.5}4.2ρ)
even during snowmelt periods. Extracted soil solution and streamwater
Β18O of NO3- were similar
and within the established range of microbially produced NO3-, demonstrating that NO3-
was formed by microbial processes. The Β15N and Β18O
of NO3- suggests that although
the two tributaries have different seasonal NO3-
concentrations, they have a similar NO3-
source.
Keywords: Β15N; Β18O; Nitrate; Nitrogen;
isotopes; Oxygen isotopes; Vermontx
Introduction
Methods
@Site description
@Sample collection
@@Precipitation
@@Streamwater
@@Soil and extracted soil solution
@Laboratory analyses
@@Isotope procedure
@Quality control
@Statistical methods
Results
@Precipitation chemistry
@Streamwater chemistry
@Soil nitrate
Discussion
@Streamwater nitrate dynamics
@Streamwater nitrate sources
@Soil nitrate
@Comparison among precipitation, streamwater and soil solution
@Snow melt
Conclusions
Acknowledgements
References