『Abstract
Previous studies on waters of a streamlet in the Vosges Mountains
(Eastern France) have shown that strontium and rare earth elements
(REE) mainly originate from preferential dissolution of apatite
during weathering. However, stream water REE patterns normalized
to apatite are still depleted in the light REE (LREE, La-Sm) pointing
to the presence of an additional LREE depleting process. Vegetation
samples are strongly enriched in LREE compared to stream water
and their Sr and Nd isotopic compositions are comparable with
those of apatite and stream water. Thus, the preferential LREE
uptake by vegetation might lead to an additional LREE depletion
of surface runoff in the forested catchment. Mass balance calculations
indicate, that the yearly LREE uptake by vegetation is comparable
with the LREE export by the streamlet and, therefore, might be
an important factor controlling LREE depletion in river water.
This is underlined by the observation that rivers from arctic
and boreal regions with sparse vegetation appears to be less depleted
in LREE than rivers from tropical environments or boreal environments
with a dense vegetation cover.』
1. Introduction
2. Site setting
3. Analytical methods
4. Results and discussion
4.1. REE and Sr-Nd isotope signatures of Strengbach waters in
the uppermost catchment
4.2. The Sr-Nd isotope signatures of vegetation
4.3. The LREE uptake by vegetation
4.4. The impact of vegetation on the REE budget of the Strengbach
catchment
4.5. The fate of vegetation hosted REE after degradation
4.6. REE absorption by vegetation at a global scale
5. Summary and conclusions
Acknowledgments
References