De Gregorio,B.T. and Sharp,T.G.(2006):
The structure and distribution of carbon in 3.5 Ga Apex chert:
Implications for the biogenicity of Earth's oldest putative microfossils.
American Mineralogist, 91, 784-789.
『35億年前のアペックス・チャート中の炭素の構造と分布:地球最古と推定される微化石の生命起源との関係』
『Abstract
The oldest putative microfossils on Earth occur in the 3.5 Ga
Apex chert of the Warrawoona Group, Western Australia. We have
analyzed disseminated interstitial carbon found within Apex chert
using transmission electron microscopy (TEM) and electron energy
loss spectroscopy (EELS) to address the controversy regarding
its state of structural disorder. We found that the carbonaceous
material is structurally amorphous, with no evidence of graphitization,
and contains aromatic domains, most likely as polyaromatic ring
structures, similar to preserved kerogen in bona fide microfossils.
In addition, amorphous carbonaceous material occurs as a grain
boundary phase between quartz crystals and within fluid inclusions
in quartz crystals, indicating that hydrocarbons moved through
the chert during crystallization and hydrothermal alteration.
The results suggest that the carbonaceous material is similar
in structure to microfossil kerogen, implying the microbe-like
features within Apex chert are also microfossils. However, this
kerogen-like material may also be produced abiotically via Fischer-Tropsch-type
(FTT) synthesis reactions in an ancient hydrothermal vent.
Keywords: Geomicrobiology; microfossil; crystal structure; kerogen;
Apex chert; Fischer-Tropsch; carbon; electron microscopy; EELS』
Introduction
Experimental methods
Results
Discussion
Acknowledgments
References cited
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