『Abstract
In all, 53 elements were analyzed in 1406 coastal sea sediment
samples collected from an area off Hokkaido and the Tohoku region
of Japan during a nationwide marine geochemical mapping project.
The spatial distribution patterns of the elemental concentrations
in coastal seas along with the existing geochemical maps in terrestrial
areas were used to define natural geochemical background variation
and mass transport processes. The terrestrial area is covered
by mafic volcanic rocks and accretionary complexes associated
with ophiolite, which has small amounts of felsic volcanic rocks
and granite. The spatial distribution patterns of elements enriched
in mafic lithologies such as Fe (Total Fe2O3) and Sc in marine environments are influenced
by adjoining terrestrial materials. The spatial distribution patterns
of Cr and Ni concentrations, which are highly abundant in ultramafic
rocks on land, are used to evaluate the mass transport from land
the sea and the dispersive processes caused by oceanic currents.
The scale of mass transport by oceanic currents occurs up to a
distance of 100-200 km from the coast along the coastal areas.
The regional differences of elements rich in felsic lithologies
such as K(K2O), Nb and La in marine sediments
are determined mainly by the relative proportion of minerals and
lithic fragments enriching felsic materials to those associated
with mafic materials. The spatial distribution of elemental concentration
is not always continuous between the land areas and coastal sea
areas. That difference is interpreted as resulting from (1) transportation
of marine sediments by oceanic currents and storm waves, (2) contribution
of volcanic materials such as tephra, (3) occurrence of shell
fragments and foraminifera tests and (4) distribution of relict
sediments of the last glacial age and early transgression age.
Contamination with Cu, Zn, Cd, As, Mo, Sn, Sb, Hg, Pb and Bi was
not observed in marine environments because the study area has
little anthropogenic activity. Terrestrial materials are the dominant
source for these metals. The Mo, Cd, Sn, Sb, Hg, P`b and Ni are
abundant in silty and clayey sediments locally because of early
diagenetic processes, authigenic precipitation and organic substances
associated with these elements. The spatial distribution of As
concentration shows exceptions: it is concentrated in some coarse
and fine sands on the shelf. The enrichment is explained by adsorption
of As, sourced from a coal field, to Fe hydroxide.』
1. Introduction
2. Study area
2.1. Coastal sea areas
2.2. Terrestrial areas
3. Materials and methods
4. Geochemical map preparation
5. Results
5.1. Spatial distribution patterns of elemental concentrations
in coastal seas and adjoining terrestrial areas
5.1.1. Spatial distribution of elements in terrestrial areas
5.1.2. Spatial distribution of elements in marine sediments
5.2. Variation of elemental concentrations in coastal sea sediments
according to particle size
6. Discussion
6.1. Mass transport processes: contribution of terrestrial
materials and transportation of sediments by coastal currents
6.2. Relict sediments formed during the last glacial age and
the early transgression age
6.3. Influence of volcanic activity
6.4. Influence of anthropogenic activity, mines, early diagenetic
processes and biogenic activity
6.5. Relationships of elemental abundance in coastal sea sediments
between regional distributions and particle size effects
6.6. Major factors determining the distribution of elements in
coastal seas
6.7. Comparison of elemental abundance in coastal sea sediments
and stream sediments
6.7.1. Controlling factors of spatial distribution of mafic
components
6.7.2. Controlling factors of spatial distribution of felsic
components
6.7.3. Controlling factors of As, CD, Mo, Sn, Sb, Hg, Pb and
Bi
7. Summary
Acknowledgements
Appendix
References