『Abstract
Some 434 stream sediment samples were collected in Central Japan
for a nationwide geochemical mapping project. The resulting geochemical
maps are compared with geological, mineral resource and land use
maps. Spatial distribution patterns of elemental concentrations
in stream sediments are determined mainly by surface geology.
Elevated elemental concentrations of alkali elements, Be, Ga,
Y, Cs, Ba, lanthanide (Ln), Tl, Th, and U are consistent with
outcrop areas of granite, felsic volcanic rock, and accretionary
complexes. High concentrations of MgO, Al2O3, P2O5,
CaO, 3d transition metals, Zn, and Sr are present in sediments
supplied from mafic volcanic rock, high pressure metamorphic rocks,
and mafic-ultramafic rocks in accretionary complexes.
A procedure is established and guidelines are set for a statistical
test suite for geochemical mapping. Analysis of variance (ANOVA)
and multiple comparison tests are effective for comparing means
among the data subsets that are classified by parent lithological
materials. Among the many procedures that have been proposed for
multiple comparison tests, the Holm procedure was selected for
this study. Multiple comparison statistically confirmed the correspondence
of elemental abundance in stream sediments with surface geologies.
However, visual interpretation of some elements is inconsistent
with results of multiple comparison. According to the Holm procedure,
the U content in stream sediments is affected not by granite,
but by felsic volcanic rock. The Holm procedure clarifies that
As, Sb, and Bi, that are not explained by the presence of mineral
deposits, are enriched significantly in samples derived from accretionary
complexes. Hydrothermal activity on the ocean floor might affect
their levels of enrichment. Significant enrichment of Cu, Zn,
Cd, Sn, Sb, Hg, and Pb observed i urban areas are also supported
by the Holm procedure. The authors inferred that these sediment
samples had been contaminated.』
1. Introduction
2. Study area
2.1. Sampling locations
2.2. Geology
3. Analytical methods
4. Results
4.1. Geochemical map preparation
4.2. Spatial distribution patterns of elemental concentrations
in stream sediments
4.2.1. The influence of surface geology
4.2.2. The influence of mineral occurrences
4.2.3. The influence of anthropogenic activity
5. Statistical analysis
5.1. Surface geology in the river basin
5.2. A statistical test applied to the geochemical mapping data
5.2.1. Normality of the distribution of elemental concentrations
in stream sediments
5.2.2. The homoscedasticity assumption
5.2.3. ample size
5.3. Application of ANOVA to the geochemical data
5.4. Application of a multiple comparison procedure to the geochemical
data
6. Discussions
6.1. The homoscedasticity problem
6.2. Normality of the distribution of elemental concentrations
6.3. The result of the Holm multiple comparison procedure to
test the effect of surface geology
6.3.1. Influence of mafic volcanic, metamorphic, and ultramafic
rocks
6.3.2. Influence of granite, felsic volcanic rocks, and accretionary
complexes
6.3.3. Influence of sedimentary rock and anthropogenic activity
7. Summary
Acknowledgments
References