『Abstract
Perchlorate is a potent thyroid hormone-disrupting compound.
Drinking water is one of the major sources of human exposure to
perchlorate. Little is known about the occurrence of perchlorate
in waters from China. In this study, water samples (n = 300) collected
from 15 locations in 13 provinces and municipalities were analyzed
for the presence of perchlorate. In addition, other inorganic
anions that commonly occur in water - iodide, bromide, and nitrate
- and the disinfection byproducts, bromate, chlorate, and chlorite
were determined by high-performance liquid chromatography interfaced
with tandem mass spectrometry. Perchlorate was detected in 86%
of the samples analyzed, at concentrations ranging from <0.02
to 54.4μg l-1 (mean±SD 2.30±6.39μg l-1;
median 0.62μg l-1). Mean concentrations of perchlorate
in tap water, groundwater, surface waters, and bottled water were
2.46, 3.04, 2.82, and 0.22μg l-1, respectively. Significant
positive correlations were found between the concentrations of
perchlorate and nitrate, perchlorate and chlorate, bromide and
iodide, and nitrate and iodide.』
(Introduction)
Materials and methods
Sample collection
Standards and reagents
Sample preparation
Instrumental analysis
Quality assurance and quality control
Results and discussion
Occurrence of perchlorate in waters from China
Occurrence of chlorate, chlorite, bromate, bromide, nitrate,
and iodide in waters from China
Global comparison of perchlorate in waters
Correlations among anions and source assessment
Human exposure to perchlorate and other anions by way of water
consumption
Conclusion
Acknowledgements
References