Wu,Q., Zhang,T., Sun,H. and Kannan,K.(2010): Perchlorate in tap water, groundwater, surface waters, and bottled water from China and its association with other inorganic anions and with disinfection byproducts. Arch. Environ. Contam. Toxicol., 58, 543-550.

『中国からの水道水・地下水・表面水・ボトル水中の過塩素酸塩およびその他の無機陰イオンおよび殺菌副産物との関連』


Abstract
 Perchlorate is a potent thyroid hormone-disrupting compound. Drinking water is one of the major sources of human exposure to perchlorate. Little is known about the occurrence of perchlorate in waters from China. In this study, water samples (n = 300) collected from 15 locations in 13 provinces and municipalities were analyzed for the presence of perchlorate. In addition, other inorganic anions that commonly occur in water - iodide, bromide, and nitrate - and the disinfection byproducts, bromate, chlorate, and chlorite were determined by high-performance liquid chromatography interfaced with tandem mass spectrometry. Perchlorate was detected in 86% of the samples analyzed, at concentrations ranging from <0.02 to 54.4μg l-1 (mean±SD 2.30±6.39μg l-1; median 0.62μg l-1). Mean concentrations of perchlorate in tap water, groundwater, surface waters, and bottled water were 2.46, 3.04, 2.82, and 0.22μg l-1, respectively. Significant positive correlations were found between the concentrations of perchlorate and nitrate, perchlorate and chlorate, bromide and iodide, and nitrate and iodide.』

(Introduction)
Materials and methods
 Sample collection
 Standards and reagents
 Sample preparation
 Instrumental analysis
 Quality assurance and quality control
Results and discussion
 Occurrence of perchlorate in waters from China
 Occurrence of chlorate, chlorite, bromate, bromide, nitrate, and iodide in waters from China
 Global comparison of perchlorate in waters
 Correlations among anions and source assessment
 Human exposure to perchlorate and other anions by way of water consumption
Conclusion
Acknowledgements
References


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