Ziegler,C.L., Murray,R.W., Hovan,S.A. and Rea,D.K.(2007): Resolving eolian, volcanogenic, and authigenic components in pelagic sediment from the Pacific Ocean. Earth and Planetary Science Letters, 254, 416-432.

『太平洋の外洋堆積物中の風成と火山性と自生の成分を明らかにする』


Abstract
 We measured major and trace element concentrations in the operationally defined, chemically extracted, residual aluminosilicate component of sediment from Ocean Drilling Program Sites 1215 and 1256 in the central and eastern equatorial Pacific Ocean and found that this residual component contains volcanogenic and authigenic aluminosilicates in addition to inferred eolian material. While the residual component younger than 20 Ma from the central Pacific (ODP Site 1215) is similar compositionally to upper continental crust and suggests an increase in the delivery of Asian dust material since 20 Ma, the residual in sediment older than 20 Ma indicates significant amounts of volcanogenic and authigenic materials. Volcanogenic debris comprises as much as 〜40% of the residual between 23-40 Ma, which coincides with the mid-Tertiary “ignimbrite flare-up” that occurred in much of western North America. The residual component extracted from the 50 Ma biogenic sediment reflects authigenic signatures (seawater-like negative cerium anomalies and elevated Fe/Si ratios). The previously interpreted increase in an andesitic detrital source in North Pacific locations may instead be authigenic material, presenting significant challenges for many paleoclimate proxies. Additionally, in the eastern Pacific (ODP Site 1256), the residual component contains 〜70% of volcanogenic material, most likely originating from Central America, and also includes refractory barite. The ability to separately identify eolian, volcanogenic, and authigenic materials in the aluminosilicate component of pelagic sediment allows resolution, respectively, of the climatic, geologic, and chemical processes contributing to the paleoceanographic archive in this critical oceanic region.

Keywords: Eolian; Authigenic; Volcanogenic; Sequential extractions; ODP Site 1215; ODP Site 1256; Pacific; Dust』

1. Introduction
2. Site description and sampling
 2.1. ODP Site 1215: Central North Pacific (0-58 Ma)
 2.2. ODP Site 1256: Eastern Equatorial Pacific (0-8 Ma)
3. Analytical procedures and multivariate statistics
 3.1. Sequential extraction
 3.2. Sediment digestion and chemical analyses
 3.3. Grain-size analysis
 3.4. Multivariate statistics
  3.4.1. Q-mode factor analysis
  3.4.2. Multiple linear regression
4. Chemical composition of the residual component
 4.1. Central Pacific (ODP Site 1215)
 4.2. Eastern Pacific (ODP Site 1256)
5. Discriminating eolian, volcanogenic debris, and authigenic clay
 5.1. Central Pacific (Site 1215): extracting from young (<20 Ma) and old (>20 Ma) red clay
 5.2. Central Pacific (Site 1215): extracting from 50 Ma nannofossil ooze
 5.3. Eastern Pacific (Site 1256): extracting from young (0-8 Ma) biogenic sediment
6. Significance for central Pacific eolian records
 6.1. Detrital contribution
 6.2. Volcanogenic and authigenic contributions
7. Summary and conclusions
Acknowledgements
Appendix A. Supplementary data
References


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