Negral,L., Moreno-Grau,S., Moreno,J., Querol,X., Viana,M.M. and Alastuey,A.(2008): Natural and anthropogenic contributions to PM10 and PM2.5 in an urban area in the western Mediterranean coast. Water Air Soil Pollut., 192, 227-238.

『西部地中海沿岸の都市域におけるPM10とPM2.5に対する自然および人為の寄与』


Abstract
 Source apportionment analysis was used to identify the factors contributing to atmospheric pollution at a monitoring location in the Southeast of Spain, a well documented area with an arid climate and high insolation favouring two sources of particular matter: secondary transformation in the atmosphere and resuspension of crustal dry soils to the air. These conditions are further complicated by numerous industrial facilities in the area of the historical city of Cartagena. This paper describes the air quality of an area which includes a zinc metallurgical industry, a petrochemical factory, an oil power station, a shipyard and natural phenomena including African dust transport and resuspension of regional and/or local crustal materials. Major and trace element concentrations in PM10 and PM2.5 were determined at two monitoring stations in Cartagena (one PM10 sampler located at a traffic hotspot and the PM2.5 sampler at a suburban station), during 2004 and 2005. Results showed that in the PM10 fraction, the zinc metallurgical activity was linked to high levels of Cd, Zn and Pb; shipyard emission was associated with high levels of Cr and Ni; and high Ni and V levels were associated with the secondary aerosol indicating the contribution from oil combustion (oil-fired power station or petrochemical facilities). In the PM2.5 size fraction, the zinc source is defined by Zn and Pb; V, Ni and As appear with the oil combustion emissions. in contrast to PM10, shipyard activity is not consistently defined. Consistent sources found in both size fractions include crustal materials and traffic emissions.

Keywords: Receptor modelling; Shipyard emissions; Tracer elements; Zinc metallurgical emissions』

1 Introduction
2 Materials and methods
 2.1 Experimental
 2.2 Statistical treatment and source contribution method
 2.3 Atmospheric transport scenarios
3 Results and discussion
 3.1 PM levels
 3.2 Chemical composition
 3.3 PM sources: Bastarreche and Santa Ana
 3.4 Characterization of ADO
4 Conclusions
Acknowledgements
References


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