Shah,M.H. and Shaheen,N.(2008): Annual and seasonal variations of trace metals in atmospheric suspended particulate matter in Islamabad, Pakistan. Water Air Soil Pollut., 190, 13-25.

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wAbstract
@Total Suspended Particulate matter (TSP) in urban atmosphere of Islamabad was collected using a high volume sampling technique for a period of one year. The nitric acid-perchloric acid extraction method was used and the metal contents were estimated by atomic absorption spectrophotometer. The highest mean concentration was found for Ca at 4.531 ƒสg/m3, followed by Na (3.905 ƒสg/m3), Fe (2.464 ƒสg/m3), Zn (2.311 ƒสg/m3), K (2.086 ƒสg/m3), Mg (0.962 ƒสg/m3), Cu (0.306 ƒสg/m3), Sb (0.157 ƒสg/m3), Pb (0.144 ƒสg/m3) and Sr (0.101 ƒสg/m3). On an average basis, the decreasing metal concentration trend was: Ca„Na„Fe„Zn„K„Mg„Cu„Sb„Pb„Sr„Mn„Co„Ni„Cr„Li„CdเAg. The TSP levels varied from a minimum of 41.8 to a maximum of 977 ƒสg/m3, with a mean value of 164 ƒสg/m3, which was found to be higher than WHO primary and secondary standards. The correlation study revealed very strong correlations (r„0.71) between Fe-Mn, Sb-Co, Na-K, Mn-Mg, Pb-Cd and Sb-Sr. Among the meteorological parameters, temperature, wind speed and pan evaporation were found to be positively correlated with TSP, Ca, Fe, K, Mg, Mn and Ag, whereas, they exhibited negative relationships with relative humidity. On the other hand, Pb, Sb, Zn, Co, Cd and Li revealed significant positive correlations with relative humidity and negative with temperature, wind speed and pan evaporation.. The major sources of airborne trace metals identified with the help of principle component analysis and cluster analysis were industrial emissions, automobile exhaust, biomass burning, oil combustion, fugitive emissions, resuspended soil dust and earth crust. The TSP and selected metals were also studied foe seasonal variations, which showed that Na, K, Zn, Cu, Pb, Sb, Sr, Co and Cd peaked during the winter and remained lowest during the summer, while Ca, Fe, Mg and Mn were recorded highest during the spring.

Keywords: AAS; Cluster analysis; Meteorological variations; Principal component analysis; Seasonal variations; TSP; Trace metalsx

1 Introduction
2 Experimental
@2.1 The study area
@2.2 Sampling
@2.3 Extraction procedure and analysis
@2.4 Statistical analysis
3 Results and discussion
@3.1 Airborne metal distribution for the annual period
@3.2 Meteorological variations during the study period
@3.3 Correlation study of TSP and metals for the annual period
@3.4 TSP and metal correlations with climatic parameters for the annual period
@3.5 Source apportionment
@3.6 Seasonal variations in airborne TSP and metal levels
4. Conclusions
Acknowledgements
References


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