『Abstract
The microstructure of nearly 200 common gem opal-A and opal-CT
samples from worldwide localities was investigated using scanning
electron microscopy (SEM). These opals do not show play-of-color,
but are valued in the gem market for their intrinsic body color.
Common opal-AG and opal-CT are primarily built from nanograins
that average 〜25 nm in diameter. Only opal-AN has a texture similar
to that of glass. In opal-AG, nanograins arrange into spheres
that have successive concentric layers, or in some cases, radial
structures. Common opal does not diffract light because its spheres
exhibit a range of sizes, are imperfectly shaped, are too large
or too small, or are not well ordered. Opal-AG spheres are typically
cemented by non-ordered nanograins, which likely result from late
stage fluid deposition. In opal-CT, nanograins have different
degrees of ordering, ranging from none (aggregation of individual
nanograins), to an intermediate stage in which they form tablets
or platelets, to the formation of lepispheres. When the structure
is built of lepispheres, they are generally cemented by non-ordered
nanograins. The degree of nanograin ordering may depend on the
growth or deposition rate imposed by the properties of the gel
from which opal settles, presumably, fast for non-ordered nanograin
structures in opal-CT to slow for the concentric arrangement of
nanograins in the spheres of opal-AG.
Keywords: Opal-A; opal-CT; common opal; structure; SEM; nanograin』
Introduction
Background
Structure of opal-AG
Cementation and section-orientation effects
Internal structure of the spheres
Structure of opal-CT
Materials and experimental methods
Material
Experimental methods
Results
Structure of common opal-AN
Structure of common opal-AG
Arrangements of spheres not giving rise to play-of-color
Internal structures of spheres
Cementation and section-orientation effects
Compaction of the spheres
Structure of common opal-CT
Random aggregation of individual nanograins
Nanograins arranged in fibers
Nanograins arranged in platelets
Nanograins arranged in lepispheres
Section-orientation effects
Discussion
Common and play-of-color opal: Where to draw the line?
The nanograin is the elementary building block of all opals,
except opal-AN
Influence of growth rate on opal structures
Imperfect conditions lead to an imperfect network, thus to common
opal
Cementation
Formation environment for gem common opal-AG and opal-CT
Future work
Acknowledgments
References cited
opal-A | amorphous | ||
opal-AN | (network), or “hyalite,” which shows only diffuse scattering of X-rays or neutrons at small angles, suggesting that it has a glass-like structure | Langer and Florke(oの頭に¨)(1974) | |
opal-AG | (gel), which is the most widespread variety. In small-angle X-ray or neutron patterns, it exhibits obvious intensity maxima superimposed upon the diffuse scattering, indicating a structure consisting of packed silica spheres. The term opal-A typically is synonymous with opal-AG. | ||
opal-CT | cristobalite-tridymite, which consists of disordered α-cristobalite with tridymitic stacking | ||
opal-C | which the proportion of cristobalite much greater than that of tridymite |