wAbstract
@This investigation represented the preliminary study to characterize
Pt and Pd concentrations and enrichment ratios in urban roadside
soils. Roadside soil samples were analyzed by ICP-MS. Data from
21 roadside topsoil samples show medians of Pt and Pd concentrations
are 2.9 and 2.8 ng g-1, respectively. These values
are higher than those of upper crust that average 0.4 and 0.4
ng g-1, respectively. The relatively lower Pt and Pd
concentrations are expected due to recent introduction of catalysts
to China compared to the prolonged use of catalysts in Europe.
Hierarchical clustering analysis indicates that Pt and Pd in Xuzhou
urban roadside soils were mainly from the traffic emissions. Computation
of enrichment ratios using the upper crust values as background
levels suggests that the roadside soils had enrichment medians
of 6.4 for Pt (range 2.5-11.75) and of 6.75 for Pd (range 2.75-9.25).
Lower Pt/Pd ratios (range 0.35-2.86) in relation to similar studies
in other countries were observed due to the different automobile
calalytic converters. In general, fine fraction (ƒ250ƒÊm) contains
higher Pt and Pd concentrations compared to the coarse fraction
(250-500ƒÊm).
Keywords: Pt; Pd; Urban roadside soil; Hierarchical cluster analysis;
Xuzhoux
Introduction
Minerals and methods
Results and discussion
@Pt and Pd concentrations
@Enrichment factors (EFs)
@Hierarchical clustering analysis
@Grain size fractions
Conclusions
References