『Abstract
Knowledge of differentiation of pollutants in urban runoff between
dissolved and particulate matter is of great concern for a successful
design of a water treatment process. Seasonal variations in pollutant
load are of equal importance. Ten metals (Al, Cd, Co, Cr, Cu,
Fe, Mn, Ni, Pb, and Zn), as dissolved and particulate bound, was
studied in the runoff from a major urban highway during a winter
season and its following summer. Studded tyres and winter salting
were expected to have an impact on the runoff water quality. The
dissolved part of al, Cd, Co, Cr, Mn and Ni was significantly
higher in winter in comparison with summer (p<0.01). For Fe, however,
the dissolved part was lower during winter. No significant difference
was found for Cu, Pb and Zn between the two seasons. The mass
concentration (mg kg-1) for all metals was significantly
higher over the summer except for Al and Co, which showed a higher
mass concentration during the winter. The concentration of selected
metals vs. total suspended solids (TSS) showed a linear relationship
(r2>0.95) during winter runoff events except for Cd.
A good correlation (r2>0.90) was also found for the
summer period for Al, Cu, Fe, Mn, Ni and Zn. It is suggested that
the metal pollutant load during winter could be assessed indirectly
by measurement of TSS.
Keywords: de-icing salt; Event Mean Concentration; metal pollution;
total suspended solids; storm water』
1. Introduction
2. Material and methods
2.1. Study area
2.2. Experimental setup and sampling
2.3. Analysis and data treatment
3. Results and discussion
3.1. Climatic conditions, electrical conductivity of water
and EMC of suspended solids
3.2. Dissolved and particulate metals
3.3. Correlation of particulate bound metals and TSS
4. Conclusions
Acknowledgements
References