『Abstract
A blackish, sandy material (‘blackish deposit’, BD) accumulates
on highway roadsides. Few years after road opening it may reach
several centimeters of depth. Comparison of BD rates of accumulation
with reported loads of suspended solids in highway runoff suggests
blackish deposits to originate both from suspended solids in road
runoff and from aerial depositions. This study of four Danish
highways shows that BD is considerably different from the original
surface (OS) materials. Compared to OS-materials, BD-materials
are clearly darker, contain more organic matter (4-8% versus around
1% in OS), have a high and less-variable content of clay and metal
oxides, and a slightly lower bulk weight and pH. Similar clay
mineralogy points to both BD and OS to be of local origin. Both
materials contain lime (calcite). The textural border between
BD and OS is also a sharp border between different levels of soil
contamination: Zn up to 330 mg/kg in BD versus 19-63 mg/kg in
OS, Pb up to 210 mg/kg versus 5-33 mg/kg, Cr up to 250 mg/kg versus
3-10 mg/kg, Cd up to twice as high in BD as in OS, Br and As markedly
higher in BD than OS, heavy mineral oils (nC25-nC35) up to 680
mg/kg versus 16-24 mg/kg, and sum of PAH up to 1.4 mg/kg versus
<0.05-0.72 mg/kg. The continuous deposition of organic matter,
calcite, metal oxides and clay suggest that BD, in addition to
particles, is able to accumulate dissolved contaminants from infiltrating
road runoff.
Keywords: soil pollution; blackish deposits; highways; heavy metals;
PAH; THC』
1. Introduction
2. Materials and methods
2.1. Sample material
2.2. Sample preparation and analysis
3. Results
3.1. Colour, bulk weight, pH, and texture
3.2. Clay mineralogy and CBD-extractable Al and Fe in clay fraction
3.3. Element distribution according to EDXRF
3.4. Heavy metals
3.5. THC and PAH
4. Discussion
4.1. Overall characteristics and composition
4.2. Wet or dry weather deposition
4.3. Mitigation potential of blackish deposits
5. Conclusions
Acknowledgement
References