wAbstract
@Urban roadside soils are important environmental media for assessing
heavy metal concentrations in urban environment. However, among
other things, heavy metal concentrations are controlled by soil
particle grain size fractions. In this study, two roadside sites
were chosen within the city of Xuzhou (China) to reflect differences
in land use. Bulk soil samples were collected and then divided
by particle diameter into five physical size fractions, 500-250,
250-125, 125-74, 74-45, 45สm. Concentrations of metals (Ti, Cr,
Al, Ga, Pb, Ba, Cd, Co, Cu, Mn, Ni, V, Zn, Mo, As, Sb, Se, Hg,
Bi, Ag) were determined for each individual fraction. These metals
could be roughly classified into two groups: anthropogenic element
(Pb, Ba, Cd, Cu, Zn, Mo, As, Sb, Se, Hg, Bi, Ag) and lithophile
element (Ti, Cr, Al, Ga, Co, Mn, Ni, V) in terms of values of
enrichment factor. As expected, higher concentrations of anthropogenic
heavy metals (Cu, Zn, Mo, As, Hg, Bi, Ag) are observed in the
finest particle grain size fraction (i.e. 45สm). However, heavy
metals Se, Sb and Ba behave independently of selected grain size
fractions. From the viewpoint of mass loading, more than 30 of
the concentrations for all anthropogenic heavy metals are contributed
by the particle grain size fractions of 45-74สm at site 1 and
more than 70 of the concentrations for all heavy metals are contributed
by the particle grain size fractions of the 45-74 and 74-125สm
at site 2. These results are important for transport of soil-bound
heavy metals and pollution control by various remedial options.
Keywords: Grain size fraction; Heavy metal partitioning; Urban
roadside soils; Loading; XRD; Xuzhou; Chinax
Introduction
Materials and methods
@Study area
@Sampling and analysis
Results and discussion
@Physicochemical properties
@Mineralogy
@Enrichment factors
@Effect of grain size fractions on heavy metal partitioning
@Heavy metal loadings
Conclusions
References