『Abstract
The impact of biomass combustion on atmospheric particulate matter
was investigated at Central and Northern European urban background
sites (Duisburg, Prague, Amsterdam, Helsinki) in 2002-2003. In
Helsinki, additional 4-week sampling campaigns were carried out
during the four seasons in 2003-2004. During campaigns fine particles
(PM2.5) and size-segregated samples were
collected with a virtual impactor and a ten-stage Berner low-pressure
impactor, respectively. From the aerosol samples monosaccharide
anhydrides (MA) were determined as source specific tracers for
biomass combustion. MA comprised 0.29-6.3% of the PM2.5
mass and 0.45-7.3% of its organic carbon content. According to
size-segregated samples, the mean diameter of a prominent MA mode
coincided with the accumulation mode of particulate mass, except
for Prague where the MA mode appeared in a slightly smaller particle
size range than the mass. The estimated contribution of biomass
combustion to the OC and PM2.5 mass concentration
was the highest in wintertime Prague, 79% and 37%, respectively.
It seems that, in addition to traffic in densely populated areas,
incomplete biomass combustion with current heating appliances
can be a major source of particulate pollution both at local and
regional scales.
Keywords: Biomass combustion; Domestic heating; Fine particles;
Monosaccharide anhydrides; Organic carbon; PM2.5』
1 Introduction
2 Experimental methods
2.1 Sampling sites and instruments
2.2 Gravimetric and chemical analysis
Gravimetric analysis
Ion chromatography (IC)
High-performance liquid chromatography mass spectrometry (HPLC-MS)
Thermal-optical transmission (TOT) method
3 Results and discussion
3.1 MA, potassium, OC and PM2.5 concentrations
3.2 Mass size distribution of MA and PM
3.3 Ionic markers of biomass combustion
3.4 The contribution of biomass combustion to OC and PM2.5
4 Conclusions and implications
Acknowledgement
References