『Abstract
It is hypothesized that episodic introductions of road salt severely
disrupt the soil nitrogen cycle at a range of spatial and temporal
scales. A field-scale study has confirmed impacts on the nitrogen
cycle in soil, soil solution and river samples. There is evidence
that ammonium-N retention on cation exchange sites has been reduced
by the presence of sodium ions, and that ammonium-N has been flushed
from the exchange sites. Increases in soil pH have been caused
in naturally acidic uplands. These have enhanced mineralization
of organic-N, especially nitrification, leading to a reduction
in the mineralizable-N pool of roadside soils. There is evidence
to support the hypothesis that organic matter content has been
lowered over decades either through desorption or dispersal processes.
Multiple drivers are identified that contribute to the disruption
of nitrogen cycling processes, but their relative importance is
difficult to quantify unequivocally. The influence of road salt
on soil and soil solution declines with distance from the highway,
but impacts on water chemistry in a local stream are still strongly
evident at some distance from the road.
Keywords: Cationic displacement; Nitrogen cycle; Road salt; Sodium
chloride』
1. Introduction
2. Materials and methods
2.1. Field site
2.2. Sample collection
2.2.1. Soil sampling
2.2.2. Soil solution sampling
2.2.3. Freshwater sampling
2.2.4. Bulk precipitation and drainage chemistry
2.3. soil analysis
2.4. Freshwater, precipitation, road drainage and soil solution
analysis
2.5. Statistical analysis
3. Results
3.1. Road drainage and bulk precipitation chemistry
3.2. Base cation and hydrogen ion occupation of the CEC
3.3. Soil pH
3.4. Soil extractable ammonium-N
3.5. Soil extractable nitrate-N
3.6. Soil loss-on ignition and C:N
3.7. soil solution sodium
3.8. Soil solution nitrate-N
3.9. Soil solution ammonium-N
3.10. Crookdale Brook
4. Discussion
5. Conclusion
Acknowledgements
References