『Abstract
This work is part of the project study for a road tunnel bypassing
the town of Genova and was aimed at evaluating the amount of asbestos
fibres in the metaophiolites belonging to the Voltri Group and
the Sestri-Voltaggio Zone (Liguria, Northern Italy). The 85 studied
rock samples (mainly mafic and ultramafic rocks) derive from exposed
outcrops and prospecting boreholes. The study of field relations
and petrographic/microtextural investigations under the optical
microscope allowed for the identification and characterisation
of asbestos-bearing settings and lithotypes. Mineralogy and concentration
of asbestos fibres in powdered specimens were determined by means
of a scanning electron microscope equipped with an energy-dispersive
X-ray spectroscopy device. These investigations were combined
with petrography on thin-section, X-ray diffraction analysis and
phase contrast optical microscopy on rock powders. Mafic and ultramafic
rocks commonly contain asbestos in concentrations below 1,000
mg/kg (considered as the contamination threshold under Italian
law). However, the fibre concentration raises abruptly within
localised zones, where the metaophiolite sequences were involved
into late ductile to brittle tectono-metamorphic events. Two groups
of asbestos-bearing settings have been so far identified in the
area: (a) fracture networks within serpentinites (dominated by
fibrous chrysotile), and (b) boudins of chlorite-tremolite schists,
likely deriving from dynamic recrystallisation of mafic rocks
under greenschist facies conditions (dominated by fibrous amphibole).
Even considering the low volumetric incidence of these settings
(metres to few tens of metres), their high asbestos content locally
controls the total fibre amount in the excavation products, thus
requiring special prevention measures during excavation, management
and final storage of the contaminated debris.
Keywords: Asbestos fibres; Metaophiolite; Voltri Group; Tunnel
debris』
Introduction
Approach and problems
Analytical methods
XRD and PCM analyses
SEM-EDS analyses
Geological setting
Voltri Group
Sestri-Noltaggio Zone and Apennine Flysched
Petrography and asbestos content
Ultramafic rocks of the Palmaro-Caffarella and Voltri Unit
Serpentinised peridotites
Serpentinite
Veins and fractures with serpentine filling
Mafic rocks of the Palmaro-Caffarella and Voltri Unit
Prasinite
Metagabbro mylonites, tectonic breccias and cataclasites
Tremolite-chlorite schists
Sediments, netasediments and metabasalts
Discussion
Forecasting the asbestos-bearing levels on geological profiles
Genesis and occurrence of asbestos minerals
Localisation of the asbestos-bearing settings
Total amount of fibres in the studied lithotypes
Variables influencing the amount of asbestos fibres in the tunnel
debris
Concluding remarks
Acknowledgments
References