『Abstract
The Urkut(Uとuの頭に´) (Hungary) manganese (Mn)
ore, hosted by Jurassic black shale, was studied using high-resolution
mineralogical, microtextural, and chemical methods. Two independent
superimposed biostructures were identified consisting of rhythmic
laminations that provide important proxies for paleoenvironments
and duration of ore formation. Millimeter-scale laminae reflect
a depositional series of Fe-rich biomats, mineralized microbially
produced sedimentary structures. These biomats formed at the sediment-water
interface under dysoxic and neutral pH conditions by enzymatic
Fe2+ oxidizing processes that may have developed on
a daily to weekly growth cycle. The early diagenetic sedimentary
ore is composed of Ca rhodochrosite, celadonite, and smectite,
and also shows a 100-μm-scale element oscillation that produces
Mn (Ca)-rich and Si(Fe clay)-rich microlaminae. This microlamination
may reflect a 10 h to daily rhythmicity produced by the growth
of microbial communities. If true, then the giant Urkut(Uとuの頭に´)
ore deposit may have formed over hundreds of years, rather than
hundreds of thousands of years as previously thought.』
Introduction
Study area and ore description
Samples
Results
Discussion
Millimeter- and micrometer-scale rhythmicities
Duration of ore formation based on millimeter-scale laminae
Duration of ore formation based on micrometer-scale oscillations
Combination of cycles
Paleoenvironmental considerations
Conclusion
Acknowledgments
References cited