『Abstract
　Until its closure in 1997, the Serra do Navio deposit, located in Amapa（後のaの頭に´） Province, Brazil, was one of the most important sources of high-grade manganese ore to the North American market. The high-grade manganese oxide ores were derived by lateritic weathering from metasedimentary manganese protoliths of the Serra do Navio Formation. The local geological context and nature of this protolith succession are not well understood, due to poor surface outcrop conditions, and intense deformation. However, based on similar age, regional tectonic setting and lithology the Paleoproterozoic volcanosedimentary succession that includes the Serra do Navio Formation is widely believed to be similar in origin and laterally equivalent to the Birimian Supergroup in West Africa. For the present investigation several diamond drill cores intersecting the protolith succession were studied. Detailed petrographic and whole rock geochemical studies permit distinction of two fundamental lithological groups comprising of a total of five lithotypes. Biotite schist and graphitic schist lithotypes are interpreted as former metapelites. A greywacke or pyroclastic protolith cannot be excluded for the biotite schist, whereas the graphitic schist certainly originated as a sulfide-rich carbonaceous mudstone. Rhodochrosite marble, Mn-calcite marble and Mn-silicate rock are grouped together as manganiferous carbonate rocks. Manganese lutite constitutes the most probable protolith for rhodochrosite marble, whereas Mn-calcite marble was derived from Mn-rich marl and Mn-silicate rock from variable mixtures of Mn-rich marl and chert.
　The sedimentary succession at the Serra do Navio deposit is similar to that encountered at many other black shale and chert-hosted Mn carbonate deposits. A metallogenetic model is proposed, predicting deposition of manganese and closely associated chert in intra-arc basins, in environments that were bypassed by distal siliciclastic (carbonaceous mud) and proximal pyroclastic/siliciclastic detritus. Positive Ce anomalies and δ¹³CVPDB values of -4.3 to -9.4 per mill suggest that manganiferous carbonates derived during suboxic diagenesis from sedimentary Mn⁴⁺ oxyhydroxide precipitates. Metamorphic alteration of manganese carbonate-chert assemblages resulted in the formation of Mn-silicates, most importantly rhodonite and tephroite; porphyroblastic spessartine formed where Mn-carbonate reacted with aluminous clay minerals. Microthermometric studies of fluid inclusions in spessartine porphyroblasts suggests that peak metamorphic conditions reached the upper greenschist facies (1-2 kbars and 400-500℃). Retrograde metamorphism is marked by partial re-carbonation, expressed by the formation of small volumes of rhodochrosite, and Mn-calcite that are closely associated with quartz, chlorite and minor amounts of sulfides related to post-metamorphic veinlets. It is this metamorphosed succession that sourced the high-grade manganese oxide ores during prolonged lateritic weathering.

Keywords: Serra do Navio manganese deposit; Brazil; Lithogeochemistry; Metamorphic petrology; Fluid inclusion microthermometry; Metallogenesis』

1. Introduction
2. Geological setting
3. Methodology
4. Petrography and mineralogy
　4.1. Biotite schist
　4.2. Graphitic schist
　4.3. Mn-silicate rock
　4.4. Mn-calcite marble
　4.5. Rhodochrosite marble
　4.6. Mineral paragenesis
5. Fluid inclusion studies
　5.1. Fluid inclusion petrography and microthermometry
　　5.1.1. Type 1: H2O-NaCl inclusions (n = 59)
　　5.1.2. Type 2: Carbonic (CH4-rich) inclusions (n = 28)
　　5.1.3. Type 3: Mixed aqueous-carbonic inclusions (n = 7)
　5.2. P-T conditions of entrapment
6. Whole rock geochemistry
　6.1. Meta-pelite group
　6.2. Mn-carbonate group
　6.3. Stable isotope geochemistry
7. Discussion and conclusion
　7.1. Metamorphic overprint
　7.2. Nature of the protolith succession
　7.3. Metallogenetic model
Acknowledgments
References