『Abstract
Manganese nodules recovered from two stratigraphic horizons of
Tortonian-Messinian (late Miocene) age in the Bahia(iの頭は´)
Inglesa Formation of north-central Chile were studied using XRD,
SEM and geochemical analysis. The dominant mineral in the nodules
is todorokite, which suggests a diagenetic, marine environment.
This is supported by field observations of nodules replacing Ophiomorpha
burrows. Preliminary, traditional statistical analysis of the
nodule geochemistry, including single element, binary and ternary
ratios, suggests that the nodules are of the supergene, deep marine
type, as also indicated by the presence of foraminifers typical
of the upper continental slope, as well as debris flow and turbidity
current deposits in an associated submarine palaeocanyon. However,
abnormally low Cu concentrations seem to contradict this interpretation,
so that additional analyses were carried out. This included multiple
discriminant analysis (MDA), as well as a new technique applied
for the first time to manganese nodules, namely artificial neutral
network analysis (ANN). In both methods central log-ratio (CLR)
normalization was applied to the raw data. The results, in particular
those of the ANN analysis, suggest that the Bahia(iの頭は´)
Inglesa nodules present a chemical signature distinct from that
of nodules described to date. A new class is therefore proposed,
namely supergene intermediate marine (partially restricted basin).
Keywords: Manganese nodules; Bahia(iの頭は´)
Inglesa Formation; Upwelling; Multiple discriminant analysis;
Neuron network analysis』
1. Introduction
2. Origin, classification and chemical characteristics of manganese
nodules
3. Geology of the Bahia(iの頭は´) Inglesa deposits
4. Petrography
5. Geochemistry
5.1. MDA analysis
5.2. ANN analysis
6. Conclusions
Acknowledgements
References