wAbstract
@Authigenic ferromanganese formations in sediments from two horizons
(0-10 and 240-250 cm) located in the low/high bioproductive transitional
zone of the Pacific Ocean were studied. In addition to the compositionally
different two types of micronodules, crusts and ferromanganese
nodules were detected in the surface horizon (0-1 cm). Three size
fractions (50-100, 100-250, and 250-500 ƒÊm) of manganese micronodules
were investigated. In terms of surface morphology, color, and
shape, the micronodules are divided into the dull round (MN1)
and angular lustrous (MN2) varieties with different mineral and
chemical compositions. The dull MN1 are enriched in Mn and depleted
in Fe as compared with the lustrous MN2. The Mn/Fe value in the
dull MN1 varies from 13 to 14. Asbolane-buserite and birnessite
are the major manganese minerals in them. The lustrous MN2 is
mainly composed of vernadite with Mn/Fe = 4.3-4.8. Relative to
the dull MN1, fraction 50-100ƒÊm of the lustrous MN2 is enriched
in Fe (2.6 times), W (1.8), Mo (3.2), Th (2.3), Ce (5.8), and
REE (1.2-1.8). Relative to counterparts from the dull MN1, separate
fractions of the lustrous MN2 are characterized by a greater compositional
difference. For example, increase in the size of micronodules
leads to decrease in contents of the following elements: Fe (by
10 rel %), Ce (2 times), W (3.1 times), Mo (2.2 times), and Co
(1.5 times). At the same time, one can see increase in contents
of other elements: Th and Cu (21 times), Ni (1.9 times), and REE
(1.2-1.6 times). Differences in the chemical and mineral compositions
of MN1 and MN2 fractions can be related to alternation of oxidative
and suboxidative conditions in the sediments owing to the input
of a labile organic matter, which serves as the major reducer,
and the allochthonous genesis of MN2.x
(Introduction)
Materials and methods
Results
@Ferromanganese nodule and ferruginous crust
@Manganese micronodules
Discussion
Conclusions
Acknowledgments
References