wAbstract
@Epidote-group minerals are monoclinic in symmetry and have topology
consistent with space group P21/m and the
general formula A2M3[T2O7][TO4](O,F)(OH,O).
Zoisite is an orthorhombic polymorph of clinozoisite Ca2Al3[Si2O7][SiO4]O(OH) and is thus not considered a member of
the epidote-group. Epidote-group minerals are divided into three
subgroups. (1) Members of the clinozoisite subgroup are
derived from the mineral clinozoisite Ca2Al3[Si2O7][SiO4]O(OH) by homovalent substitutions only. The
key cation- and anion-sites are A1 = M2+, A2 = M2+,
M1 = M3+, M2 = M3+, M3 = 3+,
O4 = O2-, O10 =(OH)-. In other words, the
dominant valence as listed above must be maintained. (2) Members
of the allanite subgroup are REE-rich minerals typified
by the eponymous mineral gallaniteh. This subgroup may be derived
from clinozoisite by homovalent substitutions and one coupled
heterovalent substitution of the type A20(REE)3+
+ M3M2+¨A2Ca2+ + M3M3+.
Thus the valences on the key sites are: A1 = M2+, A2
= M3+, M1 = M3+, M2 = M3+,
M3 = M2+, O4 = O2-, O10 = (OH)-.
(3) Members of the dollaseite subgroup are REE-rich minerals
typified by the eponymous mineral gdollaseiteh. This subgroup
may be derived from clinozoisite by homovalent substitutions and
two coupled heterovalent substitutions of the type A2(REE)3+
+ M3M2+¨A2Ca2+ + M3M3+
and M1M2+ + O4F-¨M1M3+
+ O4O2-. Thus the valences on the key sites
are: A1 = M2+, A2 = M3+, M1 =
M2+, M2 = M3+, M3 = M2+,
O4 = F-, O10 = (OH)-.
@The key cation-sites M3 and A1 (and, in principle, M2) determine
the root name. In both clinozoisite and allanite subgroups no
prefix is added to the root name if M1 = A1. The prefixes ferri,
mangani, chromo, and vanado indicate dominant Fe3+,
Mn3+, Cr3+, and V3+ on M1, respectively.
In the dollaseite subgroup no prefix is added to the root name
if M1 = Mg. Otherwise a proper prefix must be attached; the prefixes
ferro and mangano indicate dominant Fe2+ and Mn2+
at M1, respectively. The dominant cation on A2 (other than Ca)
is treated according to the Extended Levinson suffix designation.
This simple nomenclature requires renaming of the following approved
species: Niigataite (old) = clinozoisite-(Sr) (new), hancockite
(old) = epidote-(Pb) (new), tweddillite (old) = manganipiemontite-(Sr)
(new). Minor modifications are necessary for the following
species: Strontiopiemontite (old) = piemontite-(Sr) (new),
androsite-(La) (old) = manganiandrosite-(La) (new). Before
a mineral name can be assigned, the proper subgroup has to be
determined. The determination of a proper subgroup is made by
the dominating valence at M3, M1, and A2 expressed as M2+
and or M3+, not by a single, dominant ion (i.e., Fe2+,
or Mg, or Al). In addition, the dominant valence on O4: X-
or X2- must be ascertained. [M2+]A20.50,
[M3+]M30.50 ¨ clinozoisite subgroup,
[M3+ + M4+]A20.50,
[M2+]M30.50 ¨ allanite subgroup,
{[M2+]M3+M1|[M3+ +
M4+]A2}0.50 and [X-]O40.5 ¨ dollaseite subgroup. Coupled heterovalent
substitutions in epidote-group minerals require a special application
of the so-called 50 rule in solid-solution series. (1) Clinozoisite
subgroup: The dominant trivalent cation on M3 determines
the name, whereas the A2 cation appearing in the suffix has to
be selected from among the divalent cations. (2) Allanite
and dollaseite subgroups: For the sites involved in the charge
compensation of a heterovalent substitution in A2 and O4 (i.e.
M3 in the allanite subgroup; M3 and M1 in the dollaseite subgroup),
identification of the relevant end-member formula must take into
account the dominant divalent charge-compensating octahedral
cation (M2+) and not the dominant cation in these
sites.
@Formal guidelines and examples are provided in order to determine
a mineral gworking nameh from electron-microprobe analytical data.
Key-words: Nomenclature; epidote-group minerals; clinozoisite;
allanite; dollaseite.x
1. Introduction
@1.1. Some obvious problems
@1.2. Objectives
2. Historical synopsis
@2.1. Epidote and clinozoisite
@2.2. Zoisite
@2.3. Piemontite, strontiopiemontite, and tweddillite
@2.4. gTawmawiteh and mukhinite
@2.5. Hancockite and niigataite
@2.6. REE-rich epidote-group minerals
@2.7. Epidote modules in polysomatic series
3. Recommended nomenclature
@3.1. Definition of an epidote-group mineral
@@Definition
@@Annotation
@3.2. Definition of subgroups
@3.3. Role of U4+ and Th4+ in the allanite
and dollaseite subgroups
@3.4. Derivation of mineral names
@3.5. Definition of new species of epidote-group minerals
@3.6, Assigning subgroups and mineral names to solid-solution
members
@@3.6.1. Assigning subgroups
@@3.6.2. Assigning mineral names
@@@3.6.2.1. Clinozoisite subgroup
@@@3.6.2.2. Allanite and dollaseite subgroups
4. Deriving a mineral name from electron-microprobe analytical
data
@4.1. Formula normalization
@4.2. Determination of negative charges
@4.3. Charge-balance of the empirical formula
@4.4. Assignment of ionic species to the various key sites
@4.5. Subgroup and root name
@4.6. Usage of the term gpistaciteh
@4.7. Usage of the term goxyallaniteh
5. Metamictization
6. Appendix
Acknowledgement
References
Name | Old name | A1 | A2 | M1 | M2 | M3 | O4 | O10 |
Clinozoisite Clinozoisite-(Sr)* Clinozoisite-(Pb) |
Niigataite |
Ca Ca Ca |
Ca Sr Pb |
Al Al Al |
Al Al Al |
Al Al Al |
O O O |
OH OH OH |
Epidote Epidote-(Pb)* Epidote-(Sr) |
Hancockite |
Ca Ca Ca |
Ca Pb Sr |
Al Al Al |
Al Al Al |
Fe3+ Fe3+ Fe3+ |
O O O |
OH OH OH |
Ferriepidote Ferriepidote-(Sr) Ferriepidote-(Pb) |
@ |
Ca Ca Ca |
Ca Sr Pb |
Fe3+ Fe3+ Fe3+ |
Al Al Al |
Fe3+ Fe3+ Fe3+ |
O O O |
OH OH OH |
Vanadoepidote Vanadoepidote-(Sr) Vanadoepidote-(Pb) |
@ |
Ca Ca Ca |
Ca Sr Pb |
V3+ V3+ V3+ |
Al Al Al |
Fe3+ Fe3+ Fe3+ |
O O O |
OH OH OH |
Mukhinite Mukhinite-(Sr) Mukhinite-(Pb) |
@ |
Ca Ca Ca |
Ca Sr Pb |
Al Al Al |
Al Al Al |
V3+ V3+ V3+ |
O O O |
OH OH OH |
Tawmawite** | @ | Ca | Ca | Al | Al | Cr3+ | O | OH |
Chromotawmawite | @ | Ca | Ca | Cr3+ | Al | Cr3+ | O | OH |
Piemontite Piemontite-(Sr)* Piemontite-(Pb) |
Strontiopiemontite |
Ca Ca Ca |
Ca Sr Pb |
Al Al Al |
Al Al Al |
Mn3+ Mn3+ Mn3+ |
O O O |
OH OH OH |
Manganipiemontite Manganipiemontite-(Sr)* |
Tweddillite |
Ca Ca |
Ca Sr |
Mn3+ Mn3+ |
Al Al |
Mn3+ Mn3+ |
O O |
OH OH |
new root name | @ | Mn2+ | Ca | Mn3+ | Al | Mn3+ | O | OH |
* recommended new mineral names for accepted species.
** not a valid species until clear evidence for Cr0.5 pfu on M1 or M3 is presented. |
Name | Old name | A1 | A2 | M1 | M2 | M3 | O4 | O10 |
Allanite-(Ce), -(La), -(Y) Ferriallanite-(Ce) Vanadoallanite-(REE) Chromoallanite0(REE) |
@ |
Ca Ca Ca Ca |
(REE)3+ Ce3+ (REE)3+ (REE)3+ |
Al Fe3+ V3+ Cr3+ |
Al Al Al Al |
Fe2+ Fe2+ Fe2+ Fe2+ |
O O O O |
OH OH OH OH |
Dissakisite-(Ce), -(La) Ferridissakisite-(REE) Vanadodissakisite-(REE) Manganidissakisite-(REE) Chromodissakisite-(REE) |
@ |
Ca Ca Ca Ca Ca |
(REE)3+ (REE)3+ (REE)3+ (REE)3+ (REE)3+ |
Al Fe3+ V3+ Mn3+ Cr3+ |
Al Al Al Al Al |
Mg Mg Mg Mg Mg |
O O O O O |
OH OH OH OH OH |
FerriepidoteAndrosite-(REE) (new def.) Manganiandrosite-(La)*, -(Ce)** Ferriandrosite-(REE) Vanadoandrosite-(Ce)** Chromoandrosite-(REE) |
androsite |
Mn2+ Mn2+ Mn2+ Mn2+ Mn2+ |
(REE)3+ (REE)3+ (REE)3+ Ce3+ (REE)3+ |
Al Mn3+ Fe3+ V3+ Cr3+ |
Al Al Al Al Al |
Mn2+ Mn2+ Mn2+ Mn2+ Mn2+ |
O O O O O |
OH OH OH OH OH |
New root names |
@ |
Ca Ca Mn2+ Mn2+ |
(REE)3+ (REE)3+ (REE)3+ (REE)3+ |
Al Fe3+ Al Al |
Al Fe3+ Al Al |
Mn2+ Fe2+ Mg2+ Fe2+ |
O O O O |
OH OH OH OH |
* recommended new mineral names for accepted species.
** approved by CNMMN (Cenki-Tok et al., 2006): vanadoandrosite-(Ce) has originally been approved as vanadio-androsite-(Ce). |
Name | A1 | A2 | M1 | M2 | M3 | O4 | O10 |
Dllaseite-(Ce) | Ca | Ce3+ | Mg | Al | Mg | F | OH |
Khristovite-(Ce) Ferrokhristovite-(REE) Manganokhristovite-(REE) |
Ca Ca Ca |
Ce3+ (REE)3+ (REE)3+ |
Mg Fe2+ Mn2+ |
Al Al Al |
Mn2+ Mn2+ Mn2+ |
F F F |
OH OH OH |
New root name | Ca | (REE)3+ | Mg | Al | Fe2+ | F | OH |
New root name | Mn2+ | (REE)3+ | Mg | Al | Mn2+ | F | OH |