『Abstract
Quantitative determination of the degree of chemical weathering
of rocks is a fundamental task in environmental and engineering
geology, and many weathering indices based on whole-rock chemistry
have been proposed. However, most classical indices are of limited
application to granitoids in a wide area, because these lithotypes
generally exhibit wide chemical variation arising from their petrogenesis.
The chemical evolution produced during rock weathering, therefore,
overprints pre-existing magmatic chemical variation. This problem
can cause many classical weathering indices to yield misleading
results. This study proposes a method that compensates for the
influence of petrogenesis on calculation of the weathering index.
The method is based on a bivariate plot of the magmatic chemical
variation (MCV) in granitoids, and the degree of chemical weathering
(DCW). The MCV axis must be based on an element that reflects
magmatic processes and is also relatively immobile during rock
weathering. In this study TiO2 contents are
utilized for the MCV. The DCW axis is fundamentally defined by
the ratios of more-mobile to less-mobile elements during weathering,
and hence many classical indices can be applied. The improved
value of the degree of chemical weathering (DCWi)
for a weathered rock is derived by:
DCWi = s×(MCVcv - MCVl) + DCWl
where MCVl is the measured composition (e.g.
TiO2 content) of the weathered rock. DCWl denotes the ratios of more-mobile to less-mobile
elements of the weathered rock. The “s” parameter is the slope
of the least square linear regression for fresh granitoids in
the MCV-DCW relationship. MCVcv is a correction
factor which is given by the average point on the MCV axis (e.g.
average TiO2) of the fresh rocks. This method
is useful for evaluating the degree of weathering of various granitoids,
and enhances the practical application of many weathering indices.』
1. Introduction
2. Study site
3. Methods and results
3.1. Sampling
3.2. Petrography
3.3. Geochemistry
4. Discussion
4.1. Problem of classical weathering indices
4.2. A practical method to evaluate weathering degree of granitic
rocks
4.3. Estimation of the degree of chemical weathering of granitoids
5. Conclusions
Acknowledgements
Appendix A. Supplementary material
References