『Abstract
In the Rio Tinto district of the Iberian Pyrite Belt of South
Spain, the weathering of massive sulfide bodies from iron caps,
i.e., true gossans and their subsequent alteration and re-sedimentation
has resulted in iron terraces, i.e., displaced gossans. To study
the structure and evolution of both types of gossans, magnetic
investigations have been carried out with two foci: (1) the characterisation
and spatial distribution of magnetic fabrics in different mineralised
settings, including massive sulfides, gossans, and terraces, and
(2) paleomagnetic dating. Hematite has been identified as the
susceptibility carrier in all sites and magnetic fabric investigation
of four gossans reveals a vertical variation from top to bottom,
with: (1) a horizontal foliation refered to as “mature” fabric
in the uppermost part of the primary gossans, (2) highly inclined
or vertical foliation interpreted as “immature” fabric between
the uppermost and lowermost parts, and (3) a vertical foliation
interpreted to be inherited from Hercynian deformation in the
lowermost part of the profiles. In terraces, a horizontal foliation
dominates and is interpreted to be a “sedimentary” fabric. Rock
magnetic studies of gossan samples have identified goethite as
the magnetic remanence carrier for the low-temperature component,
showing either a single direction close to the present Earth field
(PEF) direction or random directions. Maghemite, hematite, and
occasionally magnetite are the remanence carriers for the stable
high-temperature component that is characterized by non PEF directions
with both normal and reversed magnetic polarities. No reliable
conclusion can be yet be drawn on the timing of terrace magnetization
due to the small number of samples. In gossans, the polarity is
reversed in the upper part and normal in the lower part. This
vertical distribution with a negative reversal test suggests remanence
formation during two distinct periods. Remanence in the upper
parts of the gossans is older than in the lower parts, indicating
that the alteration proceeded from top to bottom of the profiles.
In the upper part, the older age and the horizontal “mature” fabric
is interpreted to be a high maturation stage of massive sulfides'
alteration. In the lower part, the age is younger and the inherited
“immature” vertical Hercynian fabric indicates a weak maturation
stage. These two distinct periods may reflect changes of paleoclimate,
erosion, and/or tectonic motion.
Keywords: AMS; Iberian Pyrite Belt; Gossans; Massive sulfides;
Terraces; Magnetic fabric; Paleomagnetic dating』
Introduction
Geological setting of the Iberian Pyrite Belt
Massive sulfide metallogeny in the IPB
The gossans in the IPB
Methods and results
Sampling
Mineralogy of the gossan and massive sulfide
Magnetic fabrics study (AMS)
Anisotropy of magnetic susceptibility
Magnetic susceptibility carrier
Magnetic fabrics
Paleomagnetic study
Discussion
Magnetic fabrics in gossan from top to bottom
Age of the massive sulfides oxidation and chemical remanent magnetization
acquisition
Two-stage alteration of the massive sulfides
Gossan formation
Conclusions
Acknowledgments
References