『Abstract
Dissolution cavities in weathered pebbly quartzite of the 〜2.5-Ga
Moeda Formation at Capanema, Quadrilatero(後のaの頭に´)
Ferrifero(iの頭は´) of Minas Gerais, Brazil,
are decorated with suspended filaments of opaline silica. The
filaments sustain xenotime-hematite aggregates in the open space.
Xenotime occurs as inclusions in buds and botryoidal aggregates
of hematite. The filamentous structures consist of strand-forming
buds, hypha-like extensions, and thin strands that compose mat-like
arrangements. They resemble microbial filaments that were replaced
by opaline silica and fossilized. The occurrence of spherical
hematite as protuberances on hematite-free opaline hyphae is interpreted
as accretion of dissolved iron onto extracellular polymers. Phosphate
sites in polymeric substances expelled from the microbial filaments
might have adsorbed yttrium and heavy rare-earth elements from
groundwater to the iron-accreting polymers. These would have resulted
in botryoidal aggregates of hematite with xenotime inclusions.
The presence of authigenic xenotime in the weathering zone opens
a new possibility to constrain the evolution of lateritic profiles
by xenotime geochronology.
keywords: Biomineralization; Xenotime; Hematite; Weathering; Siliciclastic
rocks; Moeda Formation; Capanema; Minas Gerais; Brazil』
Introduction
Geological setting and sample material
Methods
Results
Discussion
Acknowledgments
References