Cabral,A.R., Koglin,N., Gomes,A.A.S.,Jr. and Lehmann,B.(2012): Xenotime-hematite aggregates on opaline filaments: evidence for biomineralization in weathered siliciclastic rocks, Capanema, Quadrilatero(後のaの頭に´) Ferrifero(iの頭は´) of Minas Gerais, Brazil. Int. J. Earth Sci., 101, 377-383.

『オパール質繊維上のゼノタイム−赤鉄鉱集合体:ブラジルのミナシジャライス州の鉄鉱石四角地帯のカパネマの風化珪質砕屑岩におけるバイオミネラリゼーション(生物鉱化作用)の証拠』


Abstract
 Dissolution cavities in weathered pebbly quartzite of the 〜2.5-Ga Moeda Formation at Capanema, Quadrilatero(後のaの頭に´) Ferrifero(iの頭は´) of Minas Gerais, Brazil, are decorated with suspended filaments of opaline silica. The filaments sustain xenotime-hematite aggregates in the open space. Xenotime occurs as inclusions in buds and botryoidal aggregates of hematite. The filamentous structures consist of strand-forming buds, hypha-like extensions, and thin strands that compose mat-like arrangements. They resemble microbial filaments that were replaced by opaline silica and fossilized. The occurrence of spherical hematite as protuberances on hematite-free opaline hyphae is interpreted as accretion of dissolved iron onto extracellular polymers. Phosphate sites in polymeric substances expelled from the microbial filaments might have adsorbed yttrium and heavy rare-earth elements from groundwater to the iron-accreting polymers. These would have resulted in botryoidal aggregates of hematite with xenotime inclusions. The presence of authigenic xenotime in the weathering zone opens a new possibility to constrain the evolution of lateritic profiles by xenotime geochronology.

keywords: Biomineralization; Xenotime; Hematite; Weathering; Siliciclastic rocks; Moeda Formation; Capanema; Minas Gerais; Brazil』

Introduction
Geological setting and sample material
Methods
Results
Discussion
Acknowledgments
References


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