『Abstract
To quantify rates of rind formation on weathering clasts under
tropical and humid and to determine factors that control weathering
reactions, we analyzed Uranium series isotope compositions and
trace element concentrations in a basaltic andesite weathering
clast collected from Basse-Terre Island in Guadeloupe. U, Th,
and Ti elemental profiles reveal that Th and Ti behave conservatively
during rind formation, but that U is added from an external source
to the rind. In the rind, weathering reactions include dissolution
of primary minerals such as pyroxene, plagioclase, and glass matrix,
as well as formation of Fe oxyhydroxides, gibbsite and minor kaolinite.
Rare earth element (REE) profiles reveal a significant Eu negative
anomaly formed during clast weathering, consistent with plagioclase
dissolution. Significant porosity forms in the rind mostly due
to plagioclase dissolution. The new porosity is inferred to allow
influx of soil water carrying externally derived, dissolved U.
Due to this influx, U precipitates along with newly formed clay
minerals and oxyhydroxides in the rind. The conservative behavior
of Th and the continuous addition of U into the rind adequately
explain the observed systematic trends of (238U/232Th)
and (230Th/232Th) activity ratios in the
rind. Rind formation rates, determined from the measured U-series
activity ratios with an open system U addition model, increase
by a factor of 〜1.3 (0.18-0.24 mm/kyr) from a low curvature to
a high curvature section (0.018-0.12 mm-1) of the core-rind
boundary, revealing that curvature affects rates of rind formation
as expected for diffusion-limited rind formation. U-series geochronometry
thus provides the first direct evidence that the curvature of
the interface controls the rate of regolith formation at the clast
scale. The weathering rates determined at the clast scale can
be reconciled with the weathering rates determined at the watershed
or soil profile scale if surface roughness equals values of approximately
1399-2200.』
1. Introduction
2. Geological setting
3. Methods
3.1. Field sampling and clast preparation
3.2. Analytical methods for U-Th isotopes
3.3. Analytical methods for trace elements
4. Results
4.1. Major and trace element profiles
4.2. U and Th activity ratios
5. Discussion
5.1. Mobility of elements during rind formation
5.2. 238U-234U-230Th disequilibrium
during rind formation
5.3. Rind formation rates calculated from 238U-234U-230Th
disequilibria
5.4. Control of curvature on rind formation rates
5.5. Comparison of chemical weathering rates to published estimates
6. Conclusions
Acknowledgements
Appendix A. Solving the continuous U addition model
References