Zheng,G., Xu,S., Liang,M., Dermatas,D. and Xu,X.(2011): Transformations of organic carbon and its impact on lead weathering in shooting range soils. Environ. Earth Sci., 64, 2241-2246.

『射撃場土壌における有機炭素の変化と鉛風化へのその影響』


Abstract
 Five soil samples collected from shooting ranges in 1998 were stored under a closed condition for 5 years. In addition to SEM and XRD investigations, the total organic carbon content (TOC), inorganic carbon content (TIC), δ13C and δ18O of carbonates and δ13C of plant remains were analyzed. The concentrations of total carbon contents, the sum of TOC and TIC, remained the same within the 5 years storage, whereas the TOC and TIC contents decreased and increased, respectively. The TIC increase is associated with a decreased TOC, suggesting a conversion of organic carbon into inorganic carbon. Such a conversion is evidenced by the presence of primary lead carbonates and carbon isotopic composition of lead carbonates. It can be concluded that soil organic matters lay an important role in the process of bullets weathering and controls migration of the elevated lead in the soil.

Keywords: Shooting range soil; Organic carbon; Inorganic carbon; Transformation』

Introduction
Samples and experiments
Results and discussion
 Mineralogical feature of soil lead and weathering products of lead bullets
 Carbon speciation
 Carbon and oxygen isotopes
 Weathering processes and mitigation of metal lead in range soils
Summary
Acknowledgments
References


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