『Abstract
Recognizing weathering effects is significant for any work carried
out on glauconites at the surface. The mineralogy and chemistry
of glauconite grains exposed to weathering in a hot arid climate
for a maximum of 42 y were studied here. The objective of the
study was to find the mineralogical and chemical differences between
weathered glauconite from the surface and fresh glauconite from
the subsurface.
One specific glauconite-bearing layer at the surface (Layer 16)
of the Abu Tartur phosphate mine, located in the Western Desert
of Egypt, was studied in detail and compared to a fresh, subsurface
glauconitic sandstone from the underground mine.
Even within this single surface layer, the brownish-green glauconite
grains vary in color and chemical composition. From top to bottom,
the grains show an increase in Fe and K and a decrease in Al and
S. In addition, the grains show an internal color zonation caused
by variation of Fe and K contents between the center and rim of
the grains. The differences in color and chemical composition
are even more pronounced between the weathered-glauconite grains
from the surface and the fresh glauconite grains from the subsurface
which are dark green and enriched in Fe and K.
The clay fractions consisted of mixed-layer glauconite (illite)-smectite,
with the surface samples containing more expandable smectite (50%)
than the subsurface samples (20%). In the charge-distribution
diagram for muscovite-pyrophyllite-celadonite, the weathered glauconite
at the surface showed a clear trend from smectitic glauconite
at the top to illitic glauconite at the bottom of the layer, whereas
the fresh subsurface sample plotted exactly in the glauconite
field.
The color, mineralogy, and chemistry indicate that the surface
samples were strongly altered by weathering processes and that
glauconite transformed progressively into Fe-rich mixed-layer
illite-smectite and then into smectites. Weathering can thus completely
reverse the glauconitization process. For any chemical and mineralogical
characterization of glauconites at the surface, these weathering
effects must be taken into consideration.
Key Words: Abu Tartur Mine; Egypt; Glauconite; Smectite; Weathering.』
Introduction
Geological setting
Materials and methods
Thin-section microscopy
X-ray diffraction
Clay-mineral analyses
X-ray fluorescence (XRF)
Electron microprobe (EMP)
Scanning electron microscope (SEM)
Results
Mineralogy and petrology of the glauconitic sandstones
Mineralogy of clay fraction
Chemical composition of the bulk samples
Chemical composition and structural formulae of glauconite grains
Discussion
Chemical and mineralogical variations of glauconite grains
within surface Layer 16
Comparison of surface and subsurface glauconite grains
Conclusions
Acknowledgments
References