wAbstract
@Building stones manufactured from contact metamorphic slates
(Fruchtschiefer slate) from Teuma (Sachsen, Germany) were
investigated for mineralogical alterations as well as for changes
in porosity and surface roughness due to weathering. After weathering
periods of several years to decades, the originally dark gray-colored
slates show pale spots of several centimeters in size at the surface
of building stones. The dark-colored and light-colored sections
of the slate show no differences in mineralogy. Surface weathering
did not result in newly precipitated minerals. It was also found
that the observed differences in color are not caused by variations
in sedimentary organic carbon concentration or in sulfide/sulfate
concentrations. Obtained results instead indicate that dark surface
sections may show a thin cover of recent organic matter (OM),
e.g., living OM, soot, dirt,etc. Microscopic investigations suggested
that this cover was exfoliated at light-colored surface sections.
The observed disaggregation of the upper 2 mm of the building
block material results in an increase in porosity. Porosity of
black (unweathered) slate is 2 vol.. Due to weathering, the
slate's pores with diameters 1Κm show a significant increase
in frequency compared to the original pore size distribution.
Porosity of weathered rock volumes increased to approx. 8 vol..
Discolored surface sections show a higher surface roughness (root-mean-square
roughness, Rq ` 1Κmj compared to dark-colored slate surfaces (Rq
` 200 nm), both data are for cleavage planes. Preferentially,
the discolored surface sections are located close to the edges
of cut stones. This and the alteration in porosity, pore size,
and surface roughness indicate that color changes of the slate
are largely influenced by rock disaggregation proceeding from
the edges into the center rather than by mineral dissolution/precipitation
processes.
Keywords: Slate weathering; Theuma Fruchtschiefer (contact slate);
Surface roughness; Rock disaggregation; Vertical scanning interferometryx
Introduction
Materials and methods
@Material
@Method
Results and discussion
@Petrography
@@Results
@@Discussion
@Mineralogy and geochemistry
@@Results
@@Discussion
@Porosity and surface roughness
@@Results
@@Discussion
Conclusions
Acknowledgments
Open access
References