『Abstract
　What role does mineralized organic C and sulfide oxidation play in weathering of silicate minerals in deep groundwater aquifers? In this study, how H2CO3, produced as a result of mineralization of organic matter during groundwater transport, affects silicate weathering in the saturated zone of the mineral soil along a 70 m-long boreal hillslope is demonstrated. Stream water measurements of base cations and δ¹⁸O are included to determine the importance of the deep groundwater system for downstream surface water. The results suggest that H2CO3 generated from organic compounds being mineralized during the lateral transport stimulates weathering at depths between 0.5 and 3 m in the soil. This finding is indicated by progressively increasing concentrations of base cations-, silica- and inorganic C (IC) in the groundwater along the hillslope that co-occur with decreasing organic C (OC) concentrations. Protons derived from sulfide oxidation appear to be an additional driver of the weathering process as indicated by a build-up of SO4^2- in the groundwater during lateral transport and a δ³⁴S‰ value of +0.26-3.76‰ in the deep groundwater indicating S inputs from pyrite. The two identified active acids in the deep groundwater are likely to control the base-flow chemistry of streams draining larger catchments (＞1 km²) as evident by δ¹⁸O signatures and base cation concentrations that overlap with that of the groundwater.』

1. Introduction
2. material and methods
　2.1. Soil-water and deep groundwater sampling along the hillslope gradient
　2.2. Stream water and precipitation sampling
　2.3. Analysis
　2.4. Conceptual view of the studied hillslope system
　2.5. Statistics
3. Result
　3.1. Groundwater chemistry and weathering processes
　3.2. Deep groundwater and its impact on base-flow chemistry
4. Discussion
　4.1. Chemical weathering processes in deep groundwater
　4.2. Groundwater chemistry and its importance for stream chemistry
　4.3. Implications for the conceptual view of chemical weathering
Acknowledgements
References