wAbstract
@To understand the effects of temperature, pH and mechanical stress
on the pressure dissolution of quartz, two experiments using monocrystalline
quartz samples were conducted. The first was a closed-fluid experiment
to investigate the effect of pH, and the second was a flow-through
experiment to investigate stress and temperature effects. To initiate
the pressure dissolution, a pair of samples was immersed in a
solution with a prescribed pH. The samples were stressed mechanically
by pressing one sample against the other. In the closed-fluid
experiments, the pH of the solution was fixed to 7, 9, 11 and
13, the applied stress was approximately 200 MPa and temperature
25. The flow-through experiments were conducted at three different
temperatures (35, 50 and 75) at the same pH 11.7. The value of
the applied stress was 7.32, 13.72, 21.42 or 25.27 MPa. During
each of these dissolution tests, the solution was regularly sampled
and analyzed by an Inductively Coupled Plasma-Atomic Emission
Spectrometry technique to measure Si-concentration. With the measured
Si-concentration, a dissolution rate constant was computed the
different pH, stress and temperature conditions. The rate constant
is proportional to pH, stress and temperature, as indicated in
the literature. It should be noted that the rate constant for
the highest stress (200 MPa) was considerably greater than the
other cases. In addition, island-channel patterns characterized
by micro-crack a few nanometers in length were seen on the dissolved
parts of the samples. The findings and the measured data in this
paper may be useful for the future development of theoretical
models for pressure dissolution and its validation.
Keywords: Quartz dissolution; ICP-AES; CLSM; Dissolution ratex
CLSM=confocal laser-scanning microscope
Introduction
Dissolution experiment
@Materials and conditions
@Closed-fluid experiment
@Flow-through experiment
@Surface observation and analysis
Results and discussions
@Surface deformation
@pH effect
@Temperature effect
@Stress effect
Conclusions
Acknowledgments
References