Chardon et al.(2006)による〔『Reactions of feldspar surfaces with aqueous solutions』(1p)から〕

『長石表面の水溶液との反応』


Abstract
 Reactions involving feldspars are of great importance in the environment, influencing geochemical cycles in many ways. Dissolution of feldspars has been widely studied in the laboratory, with attempts being made to reproduce and understand the processes of “weathering” as seen in the environment. It has long been recognised that weathering of feldspars involves the attachment and detachment of atoms at the surface of the mineral. A wide range of factors influences the reactions involved, from the composition of the feldspar to the nature of the solution, but it is generally accepted that weathering leads to the presence of a leached layer, with a composition different from both the bulk mineral and the fluid. The aim of this paper is to review recent work carried out on feldspars, focusing particularly on developing an under standing of the leached layer using both spectroscopic methods (including Secondary Ion Mass Spectroscopy and X-ray Photoelectron Spectroscopy), and microscopic imaging techniques (including Atomic Force Microscopy and Scanning Electron Microscopy) to follow changes at the mineral/solution interface. Contrasting models of surface evolution are discussed.

Keywords: feldspar; weathering; leached layer; stoichiometry; dissolution-reprecipitation』

1. Introduction
2. Determination of surface chemical composition, structure and morphology of feldspars after dissolution
 2.1. Secondary ion mass spectroscopy (SIMS)
 2.2. Ion beam techniques
 2.3. X-ray photoelectron spectroscopy (XPS)
3. Study of the surface microtopography
4. Comparisons between laboratory experiments and naturally weathered feldspars
5. Summary and overall conclusions
References



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