『Abstract
The chemical compositions of natural waters is affected by the
weathering of geologic materials at or near the surface of the
Earth. Laboratory weathering experiments of whole-rock sulfide
rocks from the Shoe-Basin Mine (SBM) and the Pennsylvania Mine
(PM) from the Peru Creek Basin, Summit County, Colorado, indicate
that the mineral composition of the sulfide rocks, changes in
pH, the duration of the experiment, and the formation of sorbents
such as Fe and Al oxyhydroxides affect the chemical composition
of the resulting solution. Carbonate minerals in the rock from
SBM provide buffering capacity to the solution, contribute to
increases in the pH and enhance the formation of Fe and Al oxyhydroxides,
which sorb cations from solution. The final solution pH obtained
in the experiments was similar to those measured in the field
(i.e., 2.8 for PM and 5.0 for SBM). At PM, acidic, metal-rich
mine effluents is discharged into Peru Creek where it mixes with
stream water. As a result, the pH of the effluent increases causing
Fe and Al oxyhydroxide and schwertmannite to precipitate. The
resulting solids sorb metal cations from the water thereby improving
the quality of the water in Peru Creek.』
1. Introduction
1.1. Geology and mineralogy of the mines studied
2. Methods
3. Results and discussion
3.1. Mineralogy of mine sulfide samples
3.2. Experimental weathering of sulfide rock from the shoe basin
mine
3.3. Experimental weathering of sulfide rock from the Pennsylvania
mine
3.4. Evolution of the experimental-weathering solutions
3.5. Mixing of effluent from the Pennsylvania mine with Peru
Creek
4. Conclusions
Acknowledgements
References