『Abstract
A simple computer model for the dissolution kinetics of crystalline
matter governed by etch-pit formation predicts different development,
paths, and status for geometric, total (BET), and reactive surface
area during the dissolution process. The model also explores the
dynamics of the dissolution rate of a given model crystal surface
as a function of the development of surface area. Because the
surface area term is used in the normalization of bulk dissolution
rates, results of this normalization reflect the large differences
explored. Based on this evaluation, we discuss the application
of the diversely defined surface area terms. In the light of this
discussion, the likelihood of an unambiguous definition or application
of reactive surface area is problematic.
The model focuses on the relationship between the variation in
total surface area and the global dissolution rate, and thus is
independent of specific surface reaction mechanisms. The actual
model calculations presented as an example in this paper utilize
experimentally determined dissolution data of three dolomite [CaMg(CO3)2] cleavage surfaces obtained
by vertical scanning interferometry (VSI). Similar data from minerals
such as calcite, feldspars, and barite can be used and make this
model applicable to a range of different crystalline phases.』
Introduction
A simple model of surface evolution
Results and discussion
Caveat and a different view on reactive surface area
Acknowledgments
References cited